A rheological method for selecting nano-kaolin powder as filler in SBR rubber
This paper shows that the stiffness ofstyrene-butadiene solid rubber with added kaolin powder is related to the yield stress of kaolin dispersion in liquid polybutadiene rubber up to the percolation threshold. For five kinds of kaolin powder, the value of τ° spans the range of 100-430 Pa, while the...
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Veröffentlicht in: | Particuology 2010-06, Vol.8 (3), p.245-250 |
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creator | Lagazzo, Alberto Lenzi, Sergio Botter, Rodolfo Cirillo, Paolo Demicheli, Fabrizio Beruto, Dario T. |
description | This paper shows that the stiffness ofstyrene-butadiene solid rubber with added kaolin powder is related to the yield stress of kaolin dispersion in liquid polybutadiene rubber up to the percolation threshold. For five kinds of kaolin powder, the value of τ° spans the range of 100-430 Pa, while the corresponding compressive elastic constant of SBR varies from 12 to 21 MPa. A relationship between τ° and △E~i^*/ER^* is proposed. Critical examination of these data infers that kaolin powder dispersed in solid rubber matrix acts as an additive which decreases the random movement of the polybutadiene chains. Consequently, dispersions of nano-particles in liquid and in solid SBR are considered to be related, thus leading to a theological method for selecting nano-particles as fillers in solid SBR. |
doi_str_mv | 10.1016/j.partic.2010.03.014 |
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For five kinds of kaolin powder, the value of τ° spans the range of 100-430 Pa, while the corresponding compressive elastic constant of SBR varies from 12 to 21 MPa. A relationship between τ° and △E~i^*/ER^* is proposed. Critical examination of these data infers that kaolin powder dispersed in solid rubber matrix acts as an additive which decreases the random movement of the polybutadiene chains. Consequently, dispersions of nano-particles in liquid and in solid SBR are considered to be related, thus leading to a theological method for selecting nano-particles as fillers in solid SBR.</description><identifier>ISSN: 1674-2001</identifier><identifier>ISSN: 1672-2515</identifier><identifier>EISSN: 2210-4291</identifier><identifier>DOI: 10.1016/j.partic.2010.03.014</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Dispersions ; Filler dispersion ; Kaolin ; Liquid polybutadiene ; Liquids ; Mathematical analysis ; Nanocomposites ; Nanomaterials ; Nanostructure ; Rheology ; Rubber ; SBR法 ; Stiffness ; Styrene–butadiene rubber (SBR) ; Yield stress ; 丁苯橡胶 ; 固体填料 ; 粉体分散 ; 纳米技术 ; 聚丁二烯橡胶 ; 高岭土粉体</subject><ispartof>Particuology, 2010-06, Vol.8 (3), p.245-250</ispartof><rights>2010 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences</rights><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c399t-c5433e0cf8779d52e88e70fcdce49202dbaaa76065469f95f74fe845b7c5dadc3</citedby><cites>FETCH-LOGICAL-c399t-c5433e0cf8779d52e88e70fcdce49202dbaaa76065469f95f74fe845b7c5dadc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/87070X/87070X.jpg</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.partic.2010.03.014$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Lagazzo, Alberto</creatorcontrib><creatorcontrib>Lenzi, Sergio</creatorcontrib><creatorcontrib>Botter, Rodolfo</creatorcontrib><creatorcontrib>Cirillo, Paolo</creatorcontrib><creatorcontrib>Demicheli, Fabrizio</creatorcontrib><creatorcontrib>Beruto, Dario T.</creatorcontrib><title>A rheological method for selecting nano-kaolin powder as filler in SBR rubber</title><title>Particuology</title><addtitle>China Particuology</addtitle><description>This paper shows that the stiffness ofstyrene-butadiene solid rubber with added kaolin powder is related to the yield stress of kaolin dispersion in liquid polybutadiene rubber up to the percolation threshold. For five kinds of kaolin powder, the value of τ° spans the range of 100-430 Pa, while the corresponding compressive elastic constant of SBR varies from 12 to 21 MPa. A relationship between τ° and △E~i^*/ER^* is proposed. Critical examination of these data infers that kaolin powder dispersed in solid rubber matrix acts as an additive which decreases the random movement of the polybutadiene chains. Consequently, dispersions of nano-particles in liquid and in solid SBR are considered to be related, thus leading to a theological method for selecting nano-particles as fillers in solid SBR.</description><subject>Dispersions</subject><subject>Filler dispersion</subject><subject>Kaolin</subject><subject>Liquid polybutadiene</subject><subject>Liquids</subject><subject>Mathematical analysis</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Rheology</subject><subject>Rubber</subject><subject>SBR法</subject><subject>Stiffness</subject><subject>Styrene–butadiene rubber (SBR)</subject><subject>Yield stress</subject><subject>丁苯橡胶</subject><subject>固体填料</subject><subject>粉体分散</subject><subject>纳米技术</subject><subject>聚丁二烯橡胶</subject><subject>高岭土粉体</subject><issn>1674-2001</issn><issn>1672-2515</issn><issn>2210-4291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkEtvEzEQx1cIJELhG3CwuCAOG8aPtbMXpFJBi1SExONseb3jjRPHTu1NC3x6HG3vnGY0-j80v6Z5TWFNgcr3u_XR5NnbNYN6Ar4GKp40K8YotIL19GmzolKJlgHQ582LUnYAkknGV83XS5K3mEKavDWBHHDeppG4lEnBgHb2cSLRxNTuTQo-kmN6GDETU4jzIdSt3n58_E7yaRgwv2yeORMKvnqcF82vz59-Xt20t9-uv1xd3raW9_3c2k5wjmDdRql-7BhuNqjA2dGi6BmwcTDGKAmyE7J3feeUcLgR3aBsN5rR8ovm3ZL7YKIzcdK7dMqxNuq_0z78HjSeSQAHyqv27aI95nR3wjLrgy8WQzAR06lo1XHZAbC-KsWitDmVktHpY_YHk_9oCvoMWu_0Alqf4zVwXUFX24fFhvXje49ZF-sxWhx9rgT1mPz_At489m5TnO4qcj0Yu6-AUXNBOyap4v8A_e2Tlg</recordid><startdate>20100601</startdate><enddate>20100601</enddate><creator>Lagazzo, Alberto</creator><creator>Lenzi, Sergio</creator><creator>Botter, Rodolfo</creator><creator>Cirillo, Paolo</creator><creator>Demicheli, Fabrizio</creator><creator>Beruto, Dario T.</creator><general>Elsevier B.V</general><general>Department of Civil,Environmental and Architectural Engineering(DICAT),University of Genooa,P.le Kennedy(Fiera del Mare),Pad.D,16129 Genoa,Italy%Artigo S.p.A.,loc.Carpeneto,17014 Cairo Montenotte(SV),Italy</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20100601</creationdate><title>A rheological method for selecting nano-kaolin powder as filler in SBR rubber</title><author>Lagazzo, Alberto ; 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For five kinds of kaolin powder, the value of τ° spans the range of 100-430 Pa, while the corresponding compressive elastic constant of SBR varies from 12 to 21 MPa. A relationship between τ° and △E~i^*/ER^* is proposed. Critical examination of these data infers that kaolin powder dispersed in solid rubber matrix acts as an additive which decreases the random movement of the polybutadiene chains. Consequently, dispersions of nano-particles in liquid and in solid SBR are considered to be related, thus leading to a theological method for selecting nano-particles as fillers in solid SBR.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.partic.2010.03.014</doi><tpages>6</tpages></addata></record> |
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subjects | Dispersions Filler dispersion Kaolin Liquid polybutadiene Liquids Mathematical analysis Nanocomposites Nanomaterials Nanostructure Rheology Rubber SBR法 Stiffness Styrene–butadiene rubber (SBR) Yield stress 丁苯橡胶 固体填料 粉体分散 纳米技术 聚丁二烯橡胶 高岭土粉体 |
title | A rheological method for selecting nano-kaolin powder as filler in SBR rubber |
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