Proton-conducting ionic liquid-based Proton Exchange Membrane Fuel Cell membranes: The key role of ionomer–ionic liquid interaction
The paper deals with the synthesis and characterisation of proton-conducting ionic liquids (PCILs) and their polymer electrolytes obtained by blending modified Nafion membranes with different concentrations of PCILs. The PCILs are obtained by the neutralization of triethylamine with different organi...
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| Veröffentlicht in: | Journal of power sources 2010-09, Vol.195 (18), p.5829-5839 |
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| container_issue | 18 |
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| container_title | Journal of power sources |
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| creator | Martinez, Mathieu Molmeret, Yannick Cointeaux, Laure Iojoiu, Cristina Leprêtre, Jean-Claude El Kissi, Nadia Judeinstein, Patrick Sanchez, Jean-Yves |
| description | The paper deals with the synthesis and characterisation of proton-conducting ionic liquids (PCILs) and their polymer electrolytes obtained by blending modified Nafion membranes with different concentrations of PCILs. The PCILs are obtained by the neutralization of triethylamine with different organic acids. The first part of the paper studies the influence of acidity and acid structure on PCIL thermal and electrochemical performance, while the second part examines membrane conductivity and reveals it to depend more on PCIL structure than on its intrinsic conductivity. At 130
°C, conductivities exceeding 10
mS
cm
−1 were obtained in fully anhydrous conditions. |
| doi_str_mv | 10.1016/j.jpowsour.2010.01.036 |
| format | Article |
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°C, conductivities exceeding 10
mS
cm
−1 were obtained in fully anhydrous conditions.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2010.01.036</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Anhydrous proton-conducting membrane ; Applied sciences ; Blending ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrolytes ; Energy ; Energy. Thermal use of fuels ; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc ; Exact sciences and technology ; Fuel cells ; High-temperature PEMFC ; Ionic liquids ; Liquids ; Membranes ; Nafion ; PCIL ; Power sources ; Synthesis</subject><ispartof>Journal of power sources, 2010-09, Vol.195 (18), p.5829-5839</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c473t-f781b8b3c22f20bf494abe9448c24f1b5d38870172a7e9d635fb51b1a021b52e3</citedby><cites>FETCH-LOGICAL-c473t-f781b8b3c22f20bf494abe9448c24f1b5d38870172a7e9d635fb51b1a021b52e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0378775310000923$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,3537,23909,23910,25118,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22869549$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Martinez, Mathieu</creatorcontrib><creatorcontrib>Molmeret, Yannick</creatorcontrib><creatorcontrib>Cointeaux, Laure</creatorcontrib><creatorcontrib>Iojoiu, Cristina</creatorcontrib><creatorcontrib>Leprêtre, Jean-Claude</creatorcontrib><creatorcontrib>El Kissi, Nadia</creatorcontrib><creatorcontrib>Judeinstein, Patrick</creatorcontrib><creatorcontrib>Sanchez, Jean-Yves</creatorcontrib><title>Proton-conducting ionic liquid-based Proton Exchange Membrane Fuel Cell membranes: The key role of ionomer–ionic liquid interaction</title><title>Journal of power sources</title><description>The paper deals with the synthesis and characterisation of proton-conducting ionic liquids (PCILs) and their polymer electrolytes obtained by blending modified Nafion membranes with different concentrations of PCILs. The PCILs are obtained by the neutralization of triethylamine with different organic acids. The first part of the paper studies the influence of acidity and acid structure on PCIL thermal and electrochemical performance, while the second part examines membrane conductivity and reveals it to depend more on PCIL structure than on its intrinsic conductivity. At 130
°C, conductivities exceeding 10
mS
cm
−1 were obtained in fully anhydrous conditions.</description><subject>Anhydrous proton-conducting membrane</subject><subject>Applied sciences</subject><subject>Blending</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrolytes</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</subject><subject>Exact sciences and technology</subject><subject>Fuel cells</subject><subject>High-temperature PEMFC</subject><subject>Ionic liquids</subject><subject>Liquids</subject><subject>Membranes</subject><subject>Nafion</subject><subject>PCIL</subject><subject>Power sources</subject><subject>Synthesis</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS0EEkPhFZA3CDYZ_JfYYQUatQWpCBZlbdnOdeshsad2AnTHpk_AG_IkeDQDYgUrS9ffPefqHISeUrKmhHYvt-vtLn0taclrRuqQ0DXh3T20okryhsm2vY9WhEvVSNnyh-hRKVtCCKWSrNDdx5zmFBuX4rC4OcQrHFIMDo_hZglDY02BAR8gfPrNXZt4Bfg9TDabCPhsgRFvYBzxdByVV_jyGvBnuMU5jYCT3wumCfLP7z_-lsYhzpBN9UzxMXrgzVjgyfE9QZ_OTi83b5uLD-fvNm8uGicknxsvFbXKcseYZ8R60QtjoRdCOSY8te3AlZKESmYk9EPHW29baqkhrH4y4Cfo-UF3l9PNAmXWUyiunl8PT0vRNZ9OKMFUJV_8k6RSSkqVUryi3QF1OZWSwetdDpPJt5oSvW9Ib_XvhvS-IU2org3VxWdHD1OcGX2Nz4XyZ5sx1fWt6Cv3-sBBjeZLgKyLCxAdDCGDm_WQwv-sfgH3hq2H</recordid><startdate>20100915</startdate><enddate>20100915</enddate><creator>Martinez, Mathieu</creator><creator>Molmeret, Yannick</creator><creator>Cointeaux, Laure</creator><creator>Iojoiu, Cristina</creator><creator>Leprêtre, Jean-Claude</creator><creator>El Kissi, Nadia</creator><creator>Judeinstein, Patrick</creator><creator>Sanchez, Jean-Yves</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>7ST</scope><scope>SOI</scope></search><sort><creationdate>20100915</creationdate><title>Proton-conducting ionic liquid-based Proton Exchange Membrane Fuel Cell membranes: The key role of ionomer–ionic liquid interaction</title><author>Martinez, Mathieu ; Molmeret, Yannick ; Cointeaux, Laure ; Iojoiu, Cristina ; Leprêtre, Jean-Claude ; El Kissi, Nadia ; Judeinstein, Patrick ; Sanchez, Jean-Yves</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c473t-f781b8b3c22f20bf494abe9448c24f1b5d38870172a7e9d635fb51b1a021b52e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Anhydrous proton-conducting membrane</topic><topic>Applied sciences</topic><topic>Blending</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrolytes</topic><topic>Energy</topic><topic>Energy. 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°C, conductivities exceeding 10
mS
cm
−1 were obtained in fully anhydrous conditions.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2010.01.036</doi><tpages>11</tpages></addata></record> |
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| identifier | ISSN: 0378-7753 |
| ispartof | Journal of power sources, 2010-09, Vol.195 (18), p.5829-5839 |
| issn | 0378-7753 1873-2755 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Anhydrous proton-conducting membrane Applied sciences Blending Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrolytes Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells High-temperature PEMFC Ionic liquids Liquids Membranes Nafion PCIL Power sources Synthesis |
| title | Proton-conducting ionic liquid-based Proton Exchange Membrane Fuel Cell membranes: The key role of ionomer–ionic liquid interaction |
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