Water Soluble Donor-Acceptor [2]Catenane that Can Switch between a Coplanar and a Gemini-Sign Conformation
When the moon is in the seventh house: A conformationally switchable donor–acceptor [2]catenane was synthesized from a dynamic combinatorial library in water. The arrangement of the π units in one of the observed conformations features an unprecedented Gemini shape, which is reminiscent of the astro...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-07, Vol.49 (31), p.5331-5334 |
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| container_issue | 31 |
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| container_title | Angewandte Chemie (International ed.) |
| container_volume | 49 |
| creator | Au-Yeung, Ho Yu Pantoş, G. Dan Sanders, Jeremy K.M |
| description | When the moon is in the seventh house: A conformationally switchable donor–acceptor [2]catenane was synthesized from a dynamic combinatorial library in water. The arrangement of the π units in one of the observed conformations features an unprecedented Gemini shape, which is reminiscent of the astrological Gemini sign (see picture). The catenane can be switched between the parallel and nonparallel conformations upon thermal, chemical, or hydrophobic stimuli. |
| doi_str_mv | 10.1002/anie.201000807 |
| format | Article |
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| ispartof | Angewandte Chemie (International ed.), 2010-07, Vol.49 (31), p.5331-5334 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_749012345 |
| source | Wiley Online Library - AutoHoldings Journals |
| subjects | catenanes host-guest systems hydrophobic effect self-assembly π interactions |
| title | Water Soluble Donor-Acceptor [2]Catenane that Can Switch between a Coplanar and a Gemini-Sign Conformation |
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