Application of Raman spectroscopy to metal-sulfide surface analysis

The surface products of electrochemically oxidized pyrite (FeS(2)) are investigated as a function of applied potential by using Raman spectroscopy. The parameters necessary for sulfur formation on the pyrite surface were determined. An optical multichannel apparatus, consisting of an argon laser, a...

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Veröffentlicht in:Applied Optics 1993-02, Vol.32 (6), p.935-938
Hauptverfasser: TURCOTTE, S. B, BENNER, R. E, RILEY, A. M, JUN LI, WADSWORTH, M. E, BODILY, D
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container_end_page 938
container_issue 6
container_start_page 935
container_title Applied Optics
container_volume 32
creator TURCOTTE, S. B
BENNER, R. E
RILEY, A. M
JUN LI
WADSWORTH, M. E
BODILY, D
description The surface products of electrochemically oxidized pyrite (FeS(2)) are investigated as a function of applied potential by using Raman spectroscopy. The parameters necessary for sulfur formation on the pyrite surface were determined. An optical multichannel apparatus, consisting of an argon laser, a triple spectrograph, and a charge-coupled-device detector, was utilized for the Raman measurements. The advantages of this system for surface characterization include high resolution and high sensitivity as well as the capability of identifying compounds and making in-situ measurements.
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source Alma/SFX Local Collection; Optica Publishing Group Journals
subjects Analytical chemistry
CHEMICAL REACTIONS
Chemistry
ELECTROMAGNETIC RADIATION
Exact sciences and technology
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
LASER RADIATION
LASER SPECTROSCOPY
MINERALS
OXIDATION
PYRITE
RADIATIONS
RAMAN SPECTROSCOPY
SENSITIVITY
Spectrometric and optical methods
SPECTROSCOPY
SULFIDE MINERALS 400102 -- Chemical & Spectral Procedures
SURFACES
title Application of Raman spectroscopy to metal-sulfide surface analysis
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