Synthesis, Spectroscopic Characterization, and Observation of Massive MetalInsulator Transitions in Nanowires of a Nonstoichiometric Vanadium Oxide Bronze

Metalinsulator transitions in strongly correlated materials, induced by varying either temperature or dopant concentration, remain a topic of enduring interest in solid-state chemistry and physics owing to their fundamental importance in answering longstanding questions regarding correlation effect...

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Veröffentlicht in:Nano letters 2010-07, Vol.10 (7), p.2448-2453
Hauptverfasser: Patridge, Christopher J, Wu, Tai-Lung, Jaye, Cherno, Ravel, Bruce, Takeuchi, Esther S, Fischer, Daniel A, Sambandamurthy, G, Banerjee, Sarbajit
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container_end_page 2453
container_issue 7
container_start_page 2448
container_title Nano letters
container_volume 10
creator Patridge, Christopher J
Wu, Tai-Lung
Jaye, Cherno
Ravel, Bruce
Takeuchi, Esther S
Fischer, Daniel A
Sambandamurthy, G
Banerjee, Sarbajit
description Metalinsulator transitions in strongly correlated materials, induced by varying either temperature or dopant concentration, remain a topic of enduring interest in solid-state chemistry and physics owing to their fundamental importance in answering longstanding questions regarding correlation effects. We note here the unprecedented observation of a four-orders-of-magnitude metalinsulator transition in single nanowires of δ-K x V2O5, when temperature is varied, which thus represents a rare new addition to the pantheon of materials exhibiting pronounced metalinsulator transitions in proximity to room temperature.
doi_str_mv 10.1021/nl100642b
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source American Chemical Society Journals
subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Electron states
Exact sciences and technology
Materials science
Metal-insulator transitions and other electronic transitions
Nanocrystalline materials
Nanoscale materials and structures: fabrication and characterization
Physics
Quantum wires
title Synthesis, Spectroscopic Characterization, and Observation of Massive MetalInsulator Transitions in Nanowires of a Nonstoichiometric Vanadium Oxide Bronze
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