Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation

Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction wa...

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Veröffentlicht in:	Journal of the American Chemical Society 2010-07, Vol.132 (29), p.9954-9955
Hauptverfasser:	Kim, Sung-Kwan, Han, Won-Sik, Kim, Tae-Jin, Kim, Tae-Young, Nam, Suk Woo, Mitoraj, Mariusz, Piekoś, Łukasz, Michalak, Artur, Hwang, Son-Jong, Kang, Sang Ook
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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