Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation
Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction wa...
Gespeichert in:
| Veröffentlicht in: | Journal of the American Chemical Society 2010-07, Vol.132 (29), p.9954-9955 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 9955 |
|---|---|
| container_issue | 29 |
| container_start_page | 9954 |
| container_title | Journal of the American Chemical Society |
| container_volume | 132 |
| creator | Kim, Sung-Kwan Han, Won-Sik Kim, Tae-Jin Kim, Tae-Young Nam, Suk Woo Mitoraj, Mariusz Piekoś, Łukasz Michalak, Artur Hwang, Son-Jong Kang, Sang Ook |
| description | Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations. |
| doi_str_mv | 10.1021/ja101685u |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_748980319</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>748980319</sourcerecordid><originalsourceid>FETCH-LOGICAL-a314t-c3e9483d75ec2ae74272491bed74c484c6dd69736efb657f9f8b762e030b03aa3</originalsourceid><addsrcrecordid>eNptkMtOwzAQRS0EgvJY8APIG4RYBPxK7Czb8ihSJbqAHVLkOBNIlcTFdkD9A9Z8Il9CoKUrVqORzlzNuQgdU3JBCaOXc00JTVTcbaEBjRmJYsqSbTQghLBIqoTvoX3v5_0qmKK7aI-ROJVCqQF6mum61kXVNXisg66XPnhcWoev4GVZOPsMrQ6VbbEt8bBpbFtpPLJOt4Dfq_CCZw5KcNCGStd49PXxOcFDE6q336NDtFPq2sPReh6gx5vrh_Ekmt7f3o2H00hzKkJkOKRC8ULGYJgGKZhkIqU5FFIYoYRJiiJJJU-gzJNYlmmpcpkwIJzkhGvND9DZKnfh7GsHPmRN5Q30Yi3Yzme9aqoIp2lPnq9I46z3_e_ZwlWNdsuMkuyny2zTZc-erFO7vIFiQ_6V1wOnK0Abn81t59pe8p-gb99hfA4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>748980319</pqid></control><display><type>article</type><title>Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation</title><source>ACS Publications</source><creator>Kim, Sung-Kwan ; Han, Won-Sik ; Kim, Tae-Jin ; Kim, Tae-Young ; Nam, Suk Woo ; Mitoraj, Mariusz ; Piekoś, Łukasz ; Michalak, Artur ; Hwang, Son-Jong ; Kang, Sang Ook</creator><creatorcontrib>Kim, Sung-Kwan ; Han, Won-Sik ; Kim, Tae-Jin ; Kim, Tae-Young ; Nam, Suk Woo ; Mitoraj, Mariusz ; Piekoś, Łukasz ; Michalak, Artur ; Hwang, Son-Jong ; Kang, Sang Ook</creatorcontrib><description>Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja101685u</identifier><identifier>PMID: 20597488</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Journal of the American Chemical Society, 2010-07, Vol.132 (29), p.9954-9955</ispartof><rights>Copyright © 2010 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a314t-c3e9483d75ec2ae74272491bed74c484c6dd69736efb657f9f8b762e030b03aa3</citedby><cites>FETCH-LOGICAL-a314t-c3e9483d75ec2ae74272491bed74c484c6dd69736efb657f9f8b762e030b03aa3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja101685u$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja101685u$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20597488$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kim, Sung-Kwan</creatorcontrib><creatorcontrib>Han, Won-Sik</creatorcontrib><creatorcontrib>Kim, Tae-Jin</creatorcontrib><creatorcontrib>Kim, Tae-Young</creatorcontrib><creatorcontrib>Nam, Suk Woo</creatorcontrib><creatorcontrib>Mitoraj, Mariusz</creatorcontrib><creatorcontrib>Piekoś, Łukasz</creatorcontrib><creatorcontrib>Michalak, Artur</creatorcontrib><creatorcontrib>Hwang, Son-Jong</creatorcontrib><creatorcontrib>Kang, Sang Ook</creatorcontrib><title>Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.</description><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNptkMtOwzAQRS0EgvJY8APIG4RYBPxK7Czb8ihSJbqAHVLkOBNIlcTFdkD9A9Z8Il9CoKUrVqORzlzNuQgdU3JBCaOXc00JTVTcbaEBjRmJYsqSbTQghLBIqoTvoX3v5_0qmKK7aI-ROJVCqQF6mum61kXVNXisg66XPnhcWoev4GVZOPsMrQ6VbbEt8bBpbFtpPLJOt4Dfq_CCZw5KcNCGStd49PXxOcFDE6q336NDtFPq2sPReh6gx5vrh_Ekmt7f3o2H00hzKkJkOKRC8ULGYJgGKZhkIqU5FFIYoYRJiiJJJU-gzJNYlmmpcpkwIJzkhGvND9DZKnfh7GsHPmRN5Q30Yi3Yzme9aqoIp2lPnq9I46z3_e_ZwlWNdsuMkuyny2zTZc-erFO7vIFiQ_6V1wOnK0Abn81t59pe8p-gb99hfA4</recordid><startdate>20100728</startdate><enddate>20100728</enddate><creator>Kim, Sung-Kwan</creator><creator>Han, Won-Sik</creator><creator>Kim, Tae-Jin</creator><creator>Kim, Tae-Young</creator><creator>Nam, Suk Woo</creator><creator>Mitoraj, Mariusz</creator><creator>Piekoś, Łukasz</creator><creator>Michalak, Artur</creator><creator>Hwang, Son-Jong</creator><creator>Kang, Sang Ook</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20100728</creationdate><title>Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation</title><author>Kim, Sung-Kwan ; Han, Won-Sik ; Kim, Tae-Jin ; Kim, Tae-Young ; Nam, Suk Woo ; Mitoraj, Mariusz ; Piekoś, Łukasz ; Michalak, Artur ; Hwang, Son-Jong ; Kang, Sang Ook</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a314t-c3e9483d75ec2ae74272491bed74c484c6dd69736efb657f9f8b762e030b03aa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Sung-Kwan</creatorcontrib><creatorcontrib>Han, Won-Sik</creatorcontrib><creatorcontrib>Kim, Tae-Jin</creatorcontrib><creatorcontrib>Kim, Tae-Young</creatorcontrib><creatorcontrib>Nam, Suk Woo</creatorcontrib><creatorcontrib>Mitoraj, Mariusz</creatorcontrib><creatorcontrib>Piekoś, Łukasz</creatorcontrib><creatorcontrib>Michalak, Artur</creatorcontrib><creatorcontrib>Hwang, Son-Jong</creatorcontrib><creatorcontrib>Kang, Sang Ook</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Sung-Kwan</au><au>Han, Won-Sik</au><au>Kim, Tae-Jin</au><au>Kim, Tae-Young</au><au>Nam, Suk Woo</au><au>Mitoraj, Mariusz</au><au>Piekoś, Łukasz</au><au>Michalak, Artur</au><au>Hwang, Son-Jong</au><au>Kang, Sang Ook</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2010-07-28</date><risdate>2010</risdate><volume>132</volume><issue>29</issue><spage>9954</spage><epage>9955</epage><pages>9954-9955</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>20597488</pmid><doi>10.1021/ja101685u</doi><tpages>2</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 2010-07, Vol.132 (29), p.9954-9955 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_748980319 |
| source | ACS Publications |
| title | Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T21%3A00%3A48IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Palladium%20Catalysts%20for%20Dehydrogenation%20of%20Ammonia%20Borane%20with%20Preferential%20B%E2%88%92H%20Activation&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Kim,%20Sung-Kwan&rft.date=2010-07-28&rft.volume=132&rft.issue=29&rft.spage=9954&rft.epage=9955&rft.pages=9954-9955&rft.issn=0002-7863&rft.eissn=1520-5126&rft_id=info:doi/10.1021/ja101685u&rft_dat=%3Cproquest_cross%3E748980319%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=748980319&rft_id=info:pmid/20597488&rfr_iscdi=true |