Preparation of Ligand-Stabilized [P₄O₄]²⁺ by Controlled Hydrolysis of a Janus Head Type Diphosphorus Trication

Preparation of Ligand-Stabilized [P₄O₄]²⁺ by Controlled Hydrolysis of a Janus Head Type Diphosphorus Trication

A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand‐stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potenti...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-08, Vol.49 (35), p.6178-6181
Hauptverfasser: Weigand, Jan J, Feldmann, Kai-Oliver, Echterhoff, Antje K.C, Ehlers, Andreas W, Lammertsma, Koop
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Sprache:eng
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cascade reactions
electrostatic activation
phosphorus
polycations
structure elucidation
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container_end_page 6181
container_issue 35
container_start_page 6178
container_title Angewandte Chemie (International ed.)
container_volume 49
creator Weigand, Jan J
Feldmann, Kai-Oliver
Echterhoff, Antje K.C
Ehlers, Andreas W
Lammertsma, Koop
description A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand‐stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems.
doi_str_mv 10.1002/anie.201001363
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subjects cascade reactions
electrostatic activation
phosphorus
polycations
structure elucidation
title Preparation of Ligand-Stabilized [P₄O₄]²⁺ by Controlled Hydrolysis of a Janus Head Type Diphosphorus Trication
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