Clusters for alkyne-azide click reactions

Clusters for alkyne-azide click reactions

The clusters Ti(6)O(4)(OPr)(8)(OOC(CH(2))(2)C[triple bond]CH)(8) and [Zr(6)O(4)(OH)(4)(OOC(CH(2))(3)C[triple bond]CH)(12)](2) with acetylenic carboxylate ligands were prepared and structurally characterized in solution and in the crystalline state. Model reactions showed that they are suitable candi...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2010-09, Vol.39 (33), p.7640-7644
Hauptverfasser: Heinz, Philipp, Puchberger, Michael, Bendova, Maria, Baumann, Stefan O, Schubert, Ulrich
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container_issue 33
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Heinz, Philipp
Puchberger, Michael
Bendova, Maria
Baumann, Stefan O
Schubert, Ulrich
description The clusters Ti(6)O(4)(OPr)(8)(OOC(CH(2))(2)C[triple bond]CH)(8) and [Zr(6)O(4)(OH)(4)(OOC(CH(2))(3)C[triple bond]CH)(12)](2) with acetylenic carboxylate ligands were prepared and structurally characterized in solution and in the crystalline state. Model reactions showed that they are suitable candidates for the formation of cluster-based inorganic-organic hybrid materials by alkyne-azide click reactions.
doi_str_mv 10.1039/c0dt00618a
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title Clusters for alkyne-azide click reactions
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