Reversible Triple-Shape Effect of Polymer Networks Containing Polypentadecalactone- and Poly(ε-caprolactone)-Segments

Reversible Triple-Shape Effect of Polymer Networks Containing Polypentadecalactone- and Poly(ε-caprolactone)-Segments

A reversible triple‐shape effect is achieved for multi‐phase polymer networks based on two different crystallizable segments. The reversibility of the two shape‐changes is based on crystallization induced elongation (CIE) occurring during cooling and melting‐induced contraction (MIC) during heating...

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Veröffentlicht in:Advanced materials (Weinheim) 2010-08, Vol.22 (31), p.3424-3429
Hauptverfasser: Zotzmann, Jörg, Behl, Marc, Hofmann, Dieter, Lendlein, Andreas
Format: Artikel
Sprache:eng
Schlagworte:
Polyesters - chemistry
Polymer Networks
Reversible Shape Change
Shape-Memory Effect
Stimuli-Sensitive Polymers
Stress, Mechanical
Temperature
Triple-Shape Effect
X-Ray Diffraction
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container_end_page 3429
container_issue 31
container_start_page 3424
container_title Advanced materials (Weinheim)
container_volume 22
creator Zotzmann, Jörg
Behl, Marc
Hofmann, Dieter
Lendlein, Andreas
description A reversible triple‐shape effect is achieved for multi‐phase polymer networks based on two different crystallizable segments. The reversibility of the two shape‐changes is based on crystallization induced elongation (CIE) occurring during cooling and melting‐induced contraction (MIC) during heating under constant stress.
doi_str_mv 10.1002/adma.200904202
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source Wiley-Blackwell Journals; MEDLINE
subjects Polyesters - chemistry
Polymer Networks
Reversible Shape Change
Shape-Memory Effect
Stimuli-Sensitive Polymers
Stress, Mechanical
Temperature
Triple-Shape Effect
X-Ray Diffraction
title Reversible Triple-Shape Effect of Polymer Networks Containing Polypentadecalactone- and Poly(ε-caprolactone)-Segments
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