Improved High-Brightness Efficiency of Phosphorescent Organic LEDs Comprising Emitter Molecules with Small Permanent Dipole Moments

Weaker triplet‐triplet annihilation (TTA) is observed in organic solid mixed systems comprising the phosphorescent emitter Ir(ppy)2(acac), which has a smaller dipole moment than the reference compound Ir(ppy)3. Spectral and time‐resolved analysis show that the weaker TTA can be explained by lower em...

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Veröffentlicht in:Advanced materials (Weinheim) 2010-08, Vol.22 (29), p.3189-3193
Hauptverfasser: Reineke, Sebastian, Rosenow, Thomas C., Lüssem, Björn, Leo, Karl
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container_end_page 3193
container_issue 29
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container_title Advanced materials (Weinheim)
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creator Reineke, Sebastian
Rosenow, Thomas C.
Lüssem, Björn
Leo, Karl
description Weaker triplet‐triplet annihilation (TTA) is observed in organic solid mixed systems comprising the phosphorescent emitter Ir(ppy)2(acac), which has a smaller dipole moment than the reference compound Ir(ppy)3. Spectral and time‐resolved analysis show that the weaker TTA can be explained by lower emitter aggregation, which reduces diffusion‐based TTA.
doi_str_mv 10.1002/adma.201000529
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subjects Agglomeration
aggregation
Coordination Complexes - chemistry
dipole moment
Dipole moments
Efficiency
Emitters
high-brightness
Hydroxybutyrates - chemistry
Iridium - chemistry
Luminescent Agents - chemistry
OLEDs
Organic solids
Pentanones - chemistry
Phosphorescence
Pyridines - chemistry
Quantum Theory
roll-off
Spectral emittance
Thermodynamics
triplet-triplet annihilation
title Improved High-Brightness Efficiency of Phosphorescent Organic LEDs Comprising Emitter Molecules with Small Permanent Dipole Moments
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