Synthesis of Asymmetric Peroxides: Transition Metal (Cu, Fe, Mn, Co) Catalyzed Peroxidation of β-Dicarbonyl Compounds with tert-Butyl Hydroperoxide

The transition metal (Cu, Fe, Mn, Co) catalyzed peroxidation of β-dicarbonyl compounds at the α position by tert-butyl hydroperoxide was discovered. A selective, experimentally convenient, and gram-scale method was developed for the synthesis of α-peroxidated derivatives of β-diketones, β-keto ester...

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Veröffentlicht in:	Journal of organic chemistry 2010-08, Vol.75 (15), p.5065-5071
Hauptverfasser:	Terent’ev, Alexander O, Borisov, Dmitry A, Yaremenko, Ivan A, Chernyshev, Vladimir V, Nikishin, Gennady I
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Ketones - chemistry Peroxides - chemical synthesis Peroxides - chemistry tert-Butylhydroperoxide - chemistry Transition Elements - chemistry
Online-Zugang:	Volltext
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