Ferrocene and Maleimide-Functionalized Disulfide Scaffolds for Self-Assembled Monolayers on Gold

A series of ferrocene-based electroactive molecules (EAMs) containing maleimide and disulfide groups in different asymmetric and branched architectures were designed and synthesized. Stable monolayers of each EAM on gold electrodes were confirmed by cyclic voltammetry. Importantly, these EAMs expand...

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Veröffentlicht in:	Organic letters 2010-08, Vol.12 (15), p.3372-3375
Hauptverfasser:	Bertin, Paul A, Ahrens, Michael J, Bhavsar, Kinjal, Georganopoulou, Dimitra, Wunder, Markus, Blackburn, Gary F, Meade, Thomas J
Format:	Artikel
Sprache:	eng
Schlagworte:	Disulfides - chemistry Electrodes Ferrous Compounds - chemistry Gold - chemistry Maleimides - chemistry Metallocenes Models, Chemical Molecular Structure
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creator	Bertin, Paul A Ahrens, Michael J Bhavsar, Kinjal Georganopoulou, Dimitra Wunder, Markus Blackburn, Gary F Meade, Thomas J
description	A series of ferrocene-based electroactive molecules (EAMs) containing maleimide and disulfide groups in different asymmetric and branched architectures were designed and synthesized. Stable monolayers of each EAM on gold electrodes were confirmed by cyclic voltammetry. Importantly, these EAMs expand the repertoire of monolayer building blocks amenable to modular biofunctionalization for applications in electrochemical biosensor fabrication.
doi_str_mv	10.1021/ol101180r
format	Article
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subjects	Disulfides - chemistry Electrodes Ferrous Compounds - chemistry Gold - chemistry Maleimides - chemistry Metallocenes Models, Chemical Molecular Structure
title	Ferrocene and Maleimide-Functionalized Disulfide Scaffolds for Self-Assembled Monolayers on Gold
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