A New Reaction of Ethylenic Double Bonds

IN prosecuting our researches on the chemistry of nitrile oxides R —C ≡ N→O, a class of compounds closely related to aliphatic diazo-compounds R —CH : N 2 and diazo-imides R —N 3 1 , we have found that benzonitrile oxide (I) in ethereal solution reacts easily, at ordinary temperature or on slight he...

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Veröffentlicht in:	Nature (London) 1950-08, Vol.166 (4214), p.226-227
Hauptverfasser:	QUILICO, A, STAGNO D'ALCONTRES, G, GRÜNANGER, P
Format:	Artikel
Sprache:	eng
Schlagworte:	Ethylenes Humanities and Social Sciences letter multidisciplinary Old Medline Science Science (multidisciplinary)
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description	IN prosecuting our researches on the chemistry of nitrile oxides R —C ≡ N→O, a class of compounds closely related to aliphatic diazo-compounds R —CH : N 2 and diazo-imides R —N 3 1 , we have found that benzonitrile oxide (I) in ethereal solution reacts easily, at ordinary temperature or on slight heating, with the double bonds of ethylenic derivatives, to give Δ 2 -isoxazolines (II): exactly in the same way that aliphatic diazo-compounds and diazo-imides combine with ethylenic derivatives yielding respectively pyrazolines and dihydro-triazoles.
doi_str_mv	10.1038/166226a0
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STAGNO D'ALCONTRES, G ; GRÜNANGER, P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c336t-7be0127345de8eb3455a7d9eb157213b63b4142cb453bbb53d77141a505cf26c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1950</creationdate><topic>Ethylenes</topic><topic>Humanities and Social Sciences</topic><topic>letter</topic><topic>multidisciplinary</topic><topic>Old Medline</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>QUILICO, A</creatorcontrib><creatorcontrib>STAGNO D'ALCONTRES, G</creatorcontrib><creatorcontrib>GRÜNANGER, P</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Nature (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>QUILICO, A</au><au>STAGNO D'ALCONTRES, G</au><au>GRÜNANGER, P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A New Reaction of Ethylenic Double Bonds</atitle><jtitle>Nature (London)</jtitle><stitle>Nature</stitle><addtitle>Nature</addtitle><date>1950-08-05</date><risdate>1950</risdate><volume>166</volume><issue>4214</issue><spage>226</spage><epage>227</epage><pages>226-227</pages><issn>0028-0836</issn><eissn>1476-4687</eissn><abstract>IN prosecuting our researches on the chemistry of nitrile oxides R —C ≡ N→O, a class of compounds closely related to aliphatic diazo-compounds R —CH : N 2 and diazo-imides R —N 3 1 , we have found that benzonitrile oxide (I) in ethereal solution reacts easily, at ordinary temperature or on slight heating, with the double bonds of ethylenic derivatives, to give Δ 2 -isoxazolines (II): exactly in the same way that aliphatic diazo-compounds and diazo-imides combine with ethylenic derivatives yielding respectively pyrazolines and dihydro-triazoles.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>15439242</pmid><doi>10.1038/166226a0</doi><tpages>2</tpages></addata></record>
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subjects	Ethylenes Humanities and Social Sciences letter multidisciplinary Old Medline Science Science (multidisciplinary)
title	A New Reaction of Ethylenic Double Bonds
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