Analysis of the effect of internal phase leakage on liquid membrane separations

A general physical model of a typical batch extraction system employing liquid surfactant membranes is developed. The model takes into account the continuous‐phase resistance and the interfacial resistance along with permeation through a composite emulsion globule. It also quantifies the loss in ext...

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Veröffentlicht in:AIChE journal 1988-05, Vol.34 (5), p.753-762
Hauptverfasser: Borwankar, R. P., Chan, C. C., Wasan, D. T., Kurzeja, R. M., Gu, Z. M., Li, N. N.
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container_end_page 762
container_issue 5
container_start_page 753
container_title AIChE journal
container_volume 34
creator Borwankar, R. P.
Chan, C. C.
Wasan, D. T.
Kurzeja, R. M.
Gu, Z. M.
Li, N. N.
description A general physical model of a typical batch extraction system employing liquid surfactant membranes is developed. The model takes into account the continuous‐phase resistance and the interfacial resistance along with permeation through a composite emulsion globule. It also quantifies the loss in extraction efficiencies by leakage of the encapsulated phase due to membrane breakage. The physical model is easily adapted to apply to the case of transport facilitation wherein the solute is reacted in the internal phase to yield products incapable of permeating through the membrane phase. Experimental data on o‐chlorophenol extraction are satisfactorily correlated with the model.
doi_str_mv 10.1002/aic.690340506
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subjects Applied sciences
Chemical engineering
chemical technology
Exact sciences and technology
leak detection
Membrane separation (reverse osmosis, dialysis...)
membranes
separators
title Analysis of the effect of internal phase leakage on liquid membrane separations
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