Core-level satellites and outer core-level multiplet splitting in Mn model compounds
We report a systematic study of the Mn 2p, 3s, and 3p core-level photoemission and satellite structures for Mn model compounds. Charge transfer from the ligand state to the 3d metal state is observed and is distinguished by prominent shake-up satellites. We also observe that the Mn 3s multiplet spli...
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| Veröffentlicht in: | Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Surfaces, and Films, 2000-07, Vol.18 (4), p.1072-1076 |
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| container_end_page | 1076 |
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| container_issue | 4 |
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| container_title | Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films |
| container_volume | 18 |
| creator | Nelson, A. J. Reynolds, John G. Roos, Joseph W. |
| description | We report a systematic study of the Mn
2p,
3s,
and
3p
core-level photoemission and satellite structures for Mn model compounds. Charge transfer from the ligand state to the
3d
metal state is observed and is distinguished by prominent shake-up satellites. We also observe that the Mn
3s
multiplet splitting becomes smaller as the Mn oxidation state increases, and that
3s–3d
electron correlation reduces the branching ratio of the
7
S:
5
S
states in the Mn
3s
spectra. In addition, as the ligand electronegativity decreases, the spin-state purity is lost in the
3s
spectra, as evidenced by peak broadening. Our results are best understood in terms of the configuration–interaction model including intrashell electron correlation, charge transfer, and final-state screening. |
| doi_str_mv | 10.1116/1.582302 |
| format | Article |
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2p,
3s,
and
3p
core-level photoemission and satellite structures for Mn model compounds. Charge transfer from the ligand state to the
3d
metal state is observed and is distinguished by prominent shake-up satellites. We also observe that the Mn
3s
multiplet splitting becomes smaller as the Mn oxidation state increases, and that
3s–3d
electron correlation reduces the branching ratio of the
7
S:
5
S
states in the Mn
3s
spectra. In addition, as the ligand electronegativity decreases, the spin-state purity is lost in the
3s
spectra, as evidenced by peak broadening. Our results are best understood in terms of the configuration–interaction model including intrashell electron correlation, charge transfer, and final-state screening.</description><identifier>ISSN: 0734-2101</identifier><identifier>EISSN: 1520-8559</identifier><identifier>DOI: 10.1116/1.582302</identifier><identifier>CODEN: JVTAD6</identifier><language>eng</language><publisher>United States</publisher><subject>Charge transfer ; Correlation methods ; ELECTRON CORRELATION ; Electron emission ; Electron transitions ; ELECTRONEGATIVITY ; ELECTRONIC STRUCTURE ; EXPERIMENTAL DATA ; LIGANDS ; LINE BROADENING ; MANGANESE OXIDES ; MATERIALS SCIENCE ; Mathematical models ; Oxidation ; PHOTOEMISSION</subject><ispartof>Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 2000-07, Vol.18 (4), p.1072-1076</ispartof><rights>American Vacuum Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c453t-304b8d7c92f6d5e007002e2de4ab71a7a8c7755f0d37f7d2df906513a00f1e8c3</citedby><cites>FETCH-LOGICAL-c453t-304b8d7c92f6d5e007002e2de4ab71a7a8c7755f0d37f7d2df906513a00f1e8c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,309,310,314,776,780,785,786,790,881,4498,23909,23910,25118,27901,27902</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/20217044$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Nelson, A. J.</creatorcontrib><creatorcontrib>Reynolds, John G.</creatorcontrib><creatorcontrib>Roos, Joseph W.</creatorcontrib><title>Core-level satellites and outer core-level multiplet splitting in Mn model compounds</title><title>Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films</title><description>We report a systematic study of the Mn
2p,
3s,
and
3p
core-level photoemission and satellite structures for Mn model compounds. Charge transfer from the ligand state to the
3d
metal state is observed and is distinguished by prominent shake-up satellites. We also observe that the Mn
3s
multiplet splitting becomes smaller as the Mn oxidation state increases, and that
3s–3d
electron correlation reduces the branching ratio of the
7
S:
5
S
states in the Mn
3s
spectra. In addition, as the ligand electronegativity decreases, the spin-state purity is lost in the
3s
spectra, as evidenced by peak broadening. Our results are best understood in terms of the configuration–interaction model including intrashell electron correlation, charge transfer, and final-state screening.</description><subject>Charge transfer</subject><subject>Correlation methods</subject><subject>ELECTRON CORRELATION</subject><subject>Electron emission</subject><subject>Electron transitions</subject><subject>ELECTRONEGATIVITY</subject><subject>ELECTRONIC STRUCTURE</subject><subject>EXPERIMENTAL DATA</subject><subject>LIGANDS</subject><subject>LINE BROADENING</subject><subject>MANGANESE OXIDES</subject><subject>MATERIALS SCIENCE</subject><subject>Mathematical models</subject><subject>Oxidation</subject><subject>PHOTOEMISSION</subject><issn>0734-2101</issn><issn>1520-8559</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNp90MtKAzEUBuAgCtYq-AgBF-pi6klm0kyXUrxBxU1dhzQXHZlJxiRT8O1NGakLwdVZnI__XBA6JzAjhMxvyIzVtAR6gCaEUShqxhaHaAK8rApKgByjkxg_AIBSmE_QeumDKVqzNS2OMpm2bZKJWDqN_ZBMwOq33w1tavrWJBz7zFLj3nDj8LPDnde5r3zX-8HpeIqOrGyjOfupU_R6f7dePharl4en5e2qUBUrU1FCtak1Vwtq55oZAJ63MlSbSm44kVzWinPGLOiSW66ptguYM1JKAEtMrcopuhhzfUyNiCqvrt6Vd86oJChQwqGqsrocVR_852BiEl0TVb5UOuOHKHjFOKEMIMurUargYwzGij40nQxfgoDYfVcQMX430-uR7qbK1Hi3t1sf9k702v5n_-R-A8VDh2M</recordid><startdate>200007</startdate><enddate>200007</enddate><creator>Nelson, A. J.</creator><creator>Reynolds, John G.</creator><creator>Roos, Joseph W.</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7TC</scope><scope>OTOTI</scope></search><sort><creationdate>200007</creationdate><title>Core-level satellites and outer core-level multiplet splitting in Mn model compounds</title><author>Nelson, A. J. ; Reynolds, John G. ; Roos, Joseph W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c453t-304b8d7c92f6d5e007002e2de4ab71a7a8c7755f0d37f7d2df906513a00f1e8c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Charge transfer</topic><topic>Correlation methods</topic><topic>ELECTRON CORRELATION</topic><topic>Electron emission</topic><topic>Electron transitions</topic><topic>ELECTRONEGATIVITY</topic><topic>ELECTRONIC STRUCTURE</topic><topic>EXPERIMENTAL DATA</topic><topic>LIGANDS</topic><topic>LINE BROADENING</topic><topic>MANGANESE OXIDES</topic><topic>MATERIALS SCIENCE</topic><topic>Mathematical models</topic><topic>Oxidation</topic><topic>PHOTOEMISSION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nelson, A. J.</creatorcontrib><creatorcontrib>Reynolds, John G.</creatorcontrib><creatorcontrib>Roos, Joseph W.</creatorcontrib><collection>CrossRef</collection><collection>Mechanical Engineering Abstracts</collection><collection>OSTI.GOV</collection><jtitle>Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nelson, A. J.</au><au>Reynolds, John G.</au><au>Roos, Joseph W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Core-level satellites and outer core-level multiplet splitting in Mn model compounds</atitle><jtitle>Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films</jtitle><date>2000-07</date><risdate>2000</risdate><volume>18</volume><issue>4</issue><spage>1072</spage><epage>1076</epage><pages>1072-1076</pages><issn>0734-2101</issn><eissn>1520-8559</eissn><coden>JVTAD6</coden><abstract>We report a systematic study of the Mn
2p,
3s,
and
3p
core-level photoemission and satellite structures for Mn model compounds. Charge transfer from the ligand state to the
3d
metal state is observed and is distinguished by prominent shake-up satellites. We also observe that the Mn
3s
multiplet splitting becomes smaller as the Mn oxidation state increases, and that
3s–3d
electron correlation reduces the branching ratio of the
7
S:
5
S
states in the Mn
3s
spectra. In addition, as the ligand electronegativity decreases, the spin-state purity is lost in the
3s
spectra, as evidenced by peak broadening. Our results are best understood in terms of the configuration–interaction model including intrashell electron correlation, charge transfer, and final-state screening.</abstract><cop>United States</cop><doi>10.1116/1.582302</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0734-2101 |
| ispartof | Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 2000-07, Vol.18 (4), p.1072-1076 |
| issn | 0734-2101 1520-8559 |
| language | eng |
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| source | AIP Journals Complete |
| subjects | Charge transfer Correlation methods ELECTRON CORRELATION Electron emission Electron transitions ELECTRONEGATIVITY ELECTRONIC STRUCTURE EXPERIMENTAL DATA LIGANDS LINE BROADENING MANGANESE OXIDES MATERIALS SCIENCE Mathematical models Oxidation PHOTOEMISSION |
| title | Core-level satellites and outer core-level multiplet splitting in Mn model compounds |
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