The Addition Reaction of Samarium Enolates and 2-Haloenolates Derived from Esters, and Amides to Imines. Totally Stereoselective Synthesis of Enantiopure 3,4-Diamino Esters or Amides

The addition reaction of samarium enolates and 2‐haloenolates derived from esters and amides to imines takes place in an efficient manner. A novel protocol to perform the addition reaction of samarium enolates derived from esters or amides to chiral 2‐aminoimines, with total stereoselectivity and wi...

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Veröffentlicht in:Advanced synthesis & catalysis 2009-11, Vol.351 (17), p.2991-3000
Hauptverfasser: Concellón, José M., Rodríguez-Solla, Humberto, Simal, Carmen, del Amo, Vicente, García-Granda, Santiago, Díaz, M. Rosario
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Sprache:eng
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