Unprecedented Binary Semiconductors Based on TCNQ: Single-Crystal X-ray Studies and Physical Properties of Cu(TCNQX2) X=Cl, Br
Single crystals of a new structure type for the M+(TCNQ)•− binary family are isolated from reactions of dihalogenated TCNQ derivatives and CuI ions (see figure; Cu: pink C: black, N: blue, Br: orange, H: light blue). The new compound Cu(TCNQCl2) exhibits the highest conductivity of the M+(TCNQ)•− se...
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| Veröffentlicht in: | Advanced materials (Weinheim) 2010-03, Vol.22 (9), p.986-989 |
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| creator | Lopez, Nazario Zhao, Hanhua Ota, Akira Prosvirin, Andrey V. Reinheimer, Eric W. Dunbar, Kim R. |
| description | Single crystals of a new structure type for the M+(TCNQ)•− binary family are isolated from reactions of dihalogenated TCNQ derivatives and CuI ions (see figure; Cu: pink C: black, N: blue, Br: orange, H: light blue). The new compound Cu(TCNQCl2) exhibits the highest conductivity of the M+(TCNQ)•− series to date, despite the larger separation of TCNQCl2 units in the stacks. Conductive properties of Cu(TCNQX2) where X = Cl, Br is attributed to charge‐carrier transport through copper ions, which is unprecedented in M+(TCNQ)•− materials. |
| doi_str_mv | 10.1002/adma.200903217 |
| format | Article |
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The new compound Cu(TCNQCl2) exhibits the highest conductivity of the M+(TCNQ)•− series to date, despite the larger separation of TCNQCl2 units in the stacks. Conductive properties of Cu(TCNQX2) where X = Cl, Br is attributed to charge‐carrier transport through copper ions, which is unprecedented in M+(TCNQ)•− materials.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.200903217</identifier><identifier>PMID: 20217825</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Charge transport ; Copper ; Copper - chemistry ; Crystallography, X-Ray ; Data storage ; Equipment Design ; Equipment Failure Analysis ; Materials Testing ; Molecular Conformation ; Nitriles - chemistry ; Semiconductors ; Structure-property relationships ; Thin films</subject><ispartof>Advanced materials (Weinheim), 2010-03, Vol.22 (9), p.986-989</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. 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Mater</addtitle><description>Single crystals of a new structure type for the M+(TCNQ)•− binary family are isolated from reactions of dihalogenated TCNQ derivatives and CuI ions (see figure; Cu: pink C: black, N: blue, Br: orange, H: light blue). The new compound Cu(TCNQCl2) exhibits the highest conductivity of the M+(TCNQ)•− series to date, despite the larger separation of TCNQCl2 units in the stacks. Conductive properties of Cu(TCNQX2) where X = Cl, Br is attributed to charge‐carrier transport through copper ions, which is unprecedented in M+(TCNQ)•− materials.</description><subject>Charge transport</subject><subject>Copper</subject><subject>Copper - chemistry</subject><subject>Crystallography, X-Ray</subject><subject>Data storage</subject><subject>Equipment Design</subject><subject>Equipment Failure Analysis</subject><subject>Materials Testing</subject><subject>Molecular Conformation</subject><subject>Nitriles - chemistry</subject><subject>Semiconductors</subject><subject>Structure-property relationships</subject><subject>Thin films</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtv1DAURi0EotPCliXyDiqRwY84sZFYzAQoSG0paquO2Fge-wZc8hjsRDAbfjuOpozYdXUl3_Md6fpD6Bklc0oIe21ca-aMEEU4o-UDNKOC0SwnSjxEM6K4yFSRywN0GOMtSVhBisfogJEESyZm6M91twlgwUE3gMNL35mwxZfQett3brRDHyJemph2fYevqvMvb_Cl7741kFVhGwfT4FUWTIoMo_MQsekcvvi-jd6m1UXoNxCG6b2vcTW-nAQrdoxXb6vmFV6GJ-hRbZoIT-_mEbr-8P6q-pidfj75VC1OM5tLUmbcWCmco5RyZ8U6t1aaWhS85mC4sLUsKFC7drZMlzDFgRtGciKhZMo5QvkRerHzbkL_c4Q46NZHC01jOujHqMucl0SWubqf5LxQLFeTc74jbehjDFDrTfBt-j5NiZ7K0VM5el9OCjy_U4_rFtwe_9dGAtQO-OUb2N6j04t3Z4v_5dku6-MAv_dZE37oouSl0DfnJ3p1xqtqeSP1V_4XfP2p2w</recordid><startdate>20100305</startdate><enddate>20100305</enddate><creator>Lopez, Nazario</creator><creator>Zhao, Hanhua</creator><creator>Ota, Akira</creator><creator>Prosvirin, Andrey V.</creator><creator>Reinheimer, Eric W.</creator><creator>Dunbar, Kim R.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20100305</creationdate><title>Unprecedented Binary Semiconductors Based on TCNQ: Single-Crystal X-ray Studies and Physical Properties of Cu(TCNQX2) X=Cl, Br</title><author>Lopez, Nazario ; Zhao, Hanhua ; Ota, Akira ; Prosvirin, Andrey V. ; Reinheimer, Eric W. ; Dunbar, Kim R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4807-3ac85dd1113dc5b4cc8af563f3ea35cf861e1cbdc7ced293e3a20408e729dd013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Charge transport</topic><topic>Copper</topic><topic>Copper - chemistry</topic><topic>Crystallography, X-Ray</topic><topic>Data storage</topic><topic>Equipment Design</topic><topic>Equipment Failure Analysis</topic><topic>Materials Testing</topic><topic>Molecular Conformation</topic><topic>Nitriles - chemistry</topic><topic>Semiconductors</topic><topic>Structure-property relationships</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lopez, Nazario</creatorcontrib><creatorcontrib>Zhao, Hanhua</creatorcontrib><creatorcontrib>Ota, Akira</creatorcontrib><creatorcontrib>Prosvirin, Andrey V.</creatorcontrib><creatorcontrib>Reinheimer, Eric W.</creatorcontrib><creatorcontrib>Dunbar, Kim R.</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lopez, Nazario</au><au>Zhao, Hanhua</au><au>Ota, Akira</au><au>Prosvirin, Andrey V.</au><au>Reinheimer, Eric W.</au><au>Dunbar, Kim R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unprecedented Binary Semiconductors Based on TCNQ: Single-Crystal X-ray Studies and Physical Properties of Cu(TCNQX2) X=Cl, Br</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv. Mater</addtitle><date>2010-03-05</date><risdate>2010</risdate><volume>22</volume><issue>9</issue><spage>986</spage><epage>989</epage><pages>986-989</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>Single crystals of a new structure type for the M+(TCNQ)•− binary family are isolated from reactions of dihalogenated TCNQ derivatives and CuI ions (see figure; Cu: pink C: black, N: blue, Br: orange, H: light blue). The new compound Cu(TCNQCl2) exhibits the highest conductivity of the M+(TCNQ)•− series to date, despite the larger separation of TCNQCl2 units in the stacks. Conductive properties of Cu(TCNQX2) where X = Cl, Br is attributed to charge‐carrier transport through copper ions, which is unprecedented in M+(TCNQ)•− materials.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>20217825</pmid><doi>10.1002/adma.200903217</doi><tpages>4</tpages></addata></record> |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Charge transport Copper Copper - chemistry Crystallography, X-Ray Data storage Equipment Design Equipment Failure Analysis Materials Testing Molecular Conformation Nitriles - chemistry Semiconductors Structure-property relationships Thin films |
| title | Unprecedented Binary Semiconductors Based on TCNQ: Single-Crystal X-ray Studies and Physical Properties of Cu(TCNQX2) X=Cl, Br |
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