Interfacial Reaction between Zn-Al-Based High-Temperature Solders and Ni Substrate

The Zn-Al(-Cu) eutectic alloys (melting point 381°C) are candidates for use as Pb-free high-temperature solders as a substitute for Pb-based solders, which are suitable for severe working environments such as the engine room of hybrid vehicles equipped with an inverter system as well as a heat engin...

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Veröffentlicht in:Journal of electronic materials 2009-01, Vol.38 (1), p.54-60
Hauptverfasser: Takaku, Yoshikazu, Makino, Komei, Watanabe, Keita, Ohnuma, Ikuo, Kainuma, Ryosuke, Yamada, Yasushi, Yagi, Yuji, Nakagawa, Ikuo, Atsumi, Takashi, Ishida, Kiyohito
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container_title Journal of electronic materials
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creator Takaku, Yoshikazu
Makino, Komei
Watanabe, Keita
Ohnuma, Ikuo
Kainuma, Ryosuke
Yamada, Yasushi
Yagi, Yuji
Nakagawa, Ikuo
Atsumi, Takashi
Ishida, Kiyohito
description The Zn-Al(-Cu) eutectic alloys (melting point 381°C) are candidates for use as Pb-free high-temperature solders as a substitute for Pb-based solders, which are suitable for severe working environments such as the engine room of hybrid vehicles equipped with an inverter system as well as a heat engine. In this study, the interfacial reaction between Zn-Al(-Cu) alloys and the Ni substrate during soldering, aging, and thermal cycling was investigated. Semiconductor chips and Ni substrates were soldered with Zn-Al(-Cu) alloys at various temperatures under a nitrogen atmosphere. The soldered assemblies were then heat-treated at 200°C and 300°C to examine the microstructural evolution at the soldered interface. The effect of severe thermal cycles between −40°C and 250°C in air on the microstructure and fracture behavior at the solder joint was investigated. Even after a 1000-cycle test, the thickness of the Al 3 Ni 2 layer formed at the interface between the Zn-Al-based solder and the Ni substrate, which is responsible for the damage of the soldered assemblies, was quite small.
doi_str_mv 10.1007/s11664-008-0528-y
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subjects Applied sciences
Brazing. Soldering
Characterization and Evaluation of Materials
Chemistry and Materials Science
Condensed matter: structure, mechanical and thermal properties
Electronics and Microelectronics
Eutectics
Exact sciences and technology
High temperature
Instrumentation
Intermetallic compounds
Joining, thermal cutting: metallurgical aspects
Lead free solders
Materials Science
Metals. Metallurgy
Optical and Electronic Materials
Physics
Solid State Physics
Structure and morphology
thickness
Substrates
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thermal cycling
Thin film structure and morphology
title Interfacial Reaction between Zn-Al-Based High-Temperature Solders and Ni Substrate
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