A Numerical Study on the Validity of the Local Equilibrium Hypothesis in Modeling Hydrogen Thermal Desorption Spectra

We present a systematic benchmark study on different numerical models for analyzing hydrogen thermal desorption spectra, by focusing on the adoption of the local equilibrium hypothesis in these models. We find that the direct numerical method of the full set of the extended mass conservation equatio...

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Veröffentlicht in:ISIJ International 2009/12/15, Vol.49(12), pp.1907-1913
Hauptverfasser: Ebihara, Ken-ichi, Kaburaki, Hideo, Suzudo, Tomoaki, Takai, Kenichi
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container_issue 12
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container_title ISIJ International
container_volume 49
creator Ebihara, Ken-ichi
Kaburaki, Hideo
Suzudo, Tomoaki
Takai, Kenichi
description We present a systematic benchmark study on different numerical models for analyzing hydrogen thermal desorption spectra, by focusing on the adoption of the local equilibrium hypothesis in these models. We find that the direct numerical method of the full set of the extended mass conservation equations is only able to predict the experimental behavior of thermal desorption spectra for pure iron in the thin specimen limit, while other models incorporating the local equilibrium hypothesis fail to predict this behavior.
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subjects Applied sciences
Exact sciences and technology
hydrogen diffusion
hydrogen state
local equilibrium
Metals. Metallurgy
numerical simulation
thermal desorption analysis
title A Numerical Study on the Validity of the Local Equilibrium Hypothesis in Modeling Hydrogen Thermal Desorption Spectra
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