Engineering Crystal Symmetry and Polar Order in Molecular Host Frameworks
A crystal design strategy is described that produces a series of solid-state molecular host frameworks with prescribed lattice metrics and polar crystallographic symmetries. This represents a significant advance in crystal engineering, which is typically limited to manipulation of only gross structu...
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| Veröffentlicht in: | Science (American Association for the Advancement of Science) 2001-11, Vol.294 (5548), p.1907-1911 |
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| container_end_page | 1911 |
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| container_issue | 5548 |
| container_start_page | 1907 |
| container_title | Science (American Association for the Advancement of Science) |
| container_volume | 294 |
| creator | Holman, K. Travis Pivovar, Adam M. Ward, Michael D. |
| description | A crystal design strategy is described that produces a series of solid-state molecular host frameworks with prescribed lattice metrics and polar crystallographic symmetries. This represents a significant advance in crystal engineering, which is typically limited to manipulation of only gross structural features. The host frameworks, constructed by connecting flexible hydrogen-bonded sheets with banana-shaped pillars, sustain one-dimensional channels that are occupied by guest molecules during crystallization. The polar host frameworks enforce the alignment of these guests into polar arrays, with properly chosen guests affording inclusion compounds that exhibit second harmonic generation because of this alignment. This protocol exemplifies a principal goal of modern organic solid-state chemistry: the precise control of crystal symmetry and structure for the attainment of a specific bulk property. |
| doi_str_mv | 10.1126/science.1064432 |
| format | Article |
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Travis ; Pivovar, Adam M. ; Ward, Michael D.</creator><creatorcontrib>Holman, K. Travis ; Pivovar, Adam M. ; Ward, Michael D.</creatorcontrib><description>A crystal design strategy is described that produces a series of solid-state molecular host frameworks with prescribed lattice metrics and polar crystallographic symmetries. This represents a significant advance in crystal engineering, which is typically limited to manipulation of only gross structural features. The host frameworks, constructed by connecting flexible hydrogen-bonded sheets with banana-shaped pillars, sustain one-dimensional channels that are occupied by guest molecules during crystallization. The polar host frameworks enforce the alignment of these guests into polar arrays, with properly chosen guests affording inclusion compounds that exhibit second harmonic generation because of this alignment. This protocol exemplifies a principal goal of modern organic solid-state chemistry: the precise control of crystal symmetry and structure for the attainment of a specific bulk property.</description><identifier>ISSN: 0036-8075</identifier><identifier>EISSN: 1095-9203</identifier><identifier>DOI: 10.1126/science.1064432</identifier><identifier>PMID: 11729312</identifier><identifier>CODEN: SCIEAS</identifier><language>eng</language><publisher>Washington, DC: American Society for the Advancement of Science</publisher><subject>Architecture ; Bricks ; Charge separation ; Chemical engineering ; Chemical engineering research ; Condensed matter: structure, mechanical and thermal properties ; Crystal structure ; Crystallography ; Crystals ; Engineering ; Exact sciences and technology ; Experiments ; Fundamental areas of phenomenology (including applications) ; Inclusions ; Inorganic compounds ; Lattice parameters ; Miscellaneous ; Molecules ; Nonlinear optical crystals ; Optical materials ; Optics ; Organic Chemistry ; Physics ; Structure ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; Symmetry ; Tetrahedrons</subject><ispartof>Science (American Association for the Advancement of Science), 2001-11, Vol.294 (5548), p.1907-1911</ispartof><rights>Copyright 2001 American Association for the Advancement of Science</rights><rights>2002 INIST-CNRS</rights><rights>COPYRIGHT 2001 American Association for the Advancement of Science</rights><rights>COPYRIGHT 2001 American Association for the Advancement of Science</rights><rights>Copyright American Association for the Advancement of Science Nov 30, 2001</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c775t-fdc55882143433b0af492d70bf1b18a8e5fbc1b18e0919ed96bcb50726eecbf33</citedby><cites>FETCH-LOGICAL-c775t-fdc55882143433b0af492d70bf1b18a8e5fbc1b18e0919ed96bcb50726eecbf33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/3085416$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/3085416$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>314,780,784,803,2884,2885,27924,27925,58017,58250</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14145579$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11729312$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Holman, K. Travis</creatorcontrib><creatorcontrib>Pivovar, Adam M.</creatorcontrib><creatorcontrib>Ward, Michael D.</creatorcontrib><title>Engineering Crystal Symmetry and Polar Order in Molecular Host Frameworks</title><title>Science (American Association for the Advancement of Science)</title><addtitle>Science</addtitle><description>A crystal design strategy is described that produces a series of solid-state molecular host frameworks with prescribed lattice metrics and polar crystallographic symmetries. This represents a significant advance in crystal engineering, which is typically limited to manipulation of only gross structural features. The host frameworks, constructed by connecting flexible hydrogen-bonded sheets with banana-shaped pillars, sustain one-dimensional channels that are occupied by guest molecules during crystallization. The polar host frameworks enforce the alignment of these guests into polar arrays, with properly chosen guests affording inclusion compounds that exhibit second harmonic generation because of this alignment. This protocol exemplifies a principal goal of modern organic solid-state chemistry: the precise control of crystal symmetry and structure for the attainment of a specific bulk property.</description><subject>Architecture</subject><subject>Bricks</subject><subject>Charge separation</subject><subject>Chemical engineering</subject><subject>Chemical engineering research</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Crystals</subject><subject>Engineering</subject><subject>Exact sciences and technology</subject><subject>Experiments</subject><subject>Fundamental areas of phenomenology (including applications)</subject><subject>Inclusions</subject><subject>Inorganic compounds</subject><subject>Lattice parameters</subject><subject>Miscellaneous</subject><subject>Molecules</subject><subject>Nonlinear optical crystals</subject><subject>Optical materials</subject><subject>Optics</subject><subject>Organic Chemistry</subject><subject>Physics</subject><subject>Structure</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Symmetry</subject><subject>Tetrahedrons</subject><issn>0036-8075</issn><issn>1095-9203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqN0s9v0zAUB_AIgVgZnLkgFE3ix2HZ_DNxjqPaukqFIg24Wo7zUqU49rATQf97XDViKqqgegdb9sdPst43SV5idIExyS-DbsFquMAoZ4ySR8kEo5JnJUH0cTJBiOaZQAU_SZ6FsEYo3pX0aXKCcUFKiskkmV_bVWsBfGtX6dRvQq9MerfpOuj9JlW2Tj87o3y69DX4tLXpR2dAD9ujWxf69MarDn46_z08T540ygR4Ma6nydeb6y_T22yxnM2nV4tMFwXvs6bWnAtBMKOM0gqphpWkLlDV4AoLJYA3ld5uAZW4hLrMK11xVJAcQFcNpafJu13fe-9-DBB62bVBgzHKghuCLGJbwmNF-fbfklBM8yL_LyS5YBgjFuHZX3DtBm_jdyWJrRAWeNvtfIdWyoBsbeN6r_QKLHhlnIWmjcdXApWEYcEjzw7wWDV0rT7k3-_5SHr41a_UEIKc3306mi6_HU0_zI6lYrbYo-eHqHbGwApkzMV0uccvd1x7F4KHRt77tlN-IzGS27zLMe9yzHt88XocyFB1UD_4MeARvBmBClqZxiur2_DgGGacF2V0r3ZuHXrn_9xTJDiLM_0N0hcMpw</recordid><startdate>20011130</startdate><enddate>20011130</enddate><creator>Holman, K. 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Travis</au><au>Pivovar, Adam M.</au><au>Ward, Michael D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Engineering Crystal Symmetry and Polar Order in Molecular Host Frameworks</atitle><jtitle>Science (American Association for the Advancement of Science)</jtitle><addtitle>Science</addtitle><date>2001-11-30</date><risdate>2001</risdate><volume>294</volume><issue>5548</issue><spage>1907</spage><epage>1911</epage><pages>1907-1911</pages><issn>0036-8075</issn><eissn>1095-9203</eissn><coden>SCIEAS</coden><abstract>A crystal design strategy is described that produces a series of solid-state molecular host frameworks with prescribed lattice metrics and polar crystallographic symmetries. This represents a significant advance in crystal engineering, which is typically limited to manipulation of only gross structural features. 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| fulltext | fulltext |
| identifier | ISSN: 0036-8075 |
| ispartof | Science (American Association for the Advancement of Science), 2001-11, Vol.294 (5548), p.1907-1911 |
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| language | eng |
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| source | JSTOR Archive Collection A-Z Listing; American Association for the Advancement of Science |
| subjects | Architecture Bricks Charge separation Chemical engineering Chemical engineering research Condensed matter: structure, mechanical and thermal properties Crystal structure Crystallography Crystals Engineering Exact sciences and technology Experiments Fundamental areas of phenomenology (including applications) Inclusions Inorganic compounds Lattice parameters Miscellaneous Molecules Nonlinear optical crystals Optical materials Optics Organic Chemistry Physics Structure Structure of solids and liquids crystallography Structure of specific crystalline solids Symmetry Tetrahedrons |
| title | Engineering Crystal Symmetry and Polar Order in Molecular Host Frameworks |
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