Molecular container compounds
Rigid, hollow organic host compounds have been designed and synthesized with interior cavities large enough to incarcerate organic guest compounds. Some of these hosts are closed-surface spheres whose guest molecules are permanently incarcerated during synthesis. Other hosts contain portals in their...
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Veröffentlicht in: | Nature (London) 1992-03, Vol.356 (6364), p.29-36 |
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description | Rigid, hollow organic host compounds have been designed and synthesized with interior cavities large enough to incarcerate organic guest compounds. Some of these hosts are closed-surface spheres whose guest molecules are permanently incarcerated during synthesis. Other hosts contain portals in their shells, shaped to allow the passage only of complementary guest molecules between the inner and bulk phases. The inner phases uniquely constrain guest movements, provide a medium for reactions, and shelter molecules that self-destruct in bulk phases. |
doi_str_mv | 10.1038/356029a0 |
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Some of these hosts are closed-surface spheres whose guest molecules are permanently incarcerated during synthesis. Other hosts contain portals in their shells, shaped to allow the passage only of complementary guest molecules between the inner and bulk phases. The inner phases uniquely constrain guest movements, provide a medium for reactions, and shelter molecules that self-destruct in bulk phases.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><doi>10.1038/356029a0</doi><tpages>8</tpages></addata></record> |
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subjects | Biochemistry Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Humanities and Social Sciences Molecules multidisciplinary Organic chemistry Organic compounds Preparations and properties review-article Science Science (multidisciplinary) |
title | Molecular container compounds |
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