Atom transfer radical polymerization and copolymerization of vinyl acetate catalyzed by copper halide/terpyridine

Copper-mediated atom transfer radical polymerization (ATRP) is versatile for living polymerizations of a wide range of monomers, but ATRP of vinyl acetate (VAc) remains challenging due to the low homolytic cleavage activity of the carbon-halide bond of the dormant poly(vinyl acetate) (PVAc) chains a...

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Veröffentlicht in:	AIChE journal 2009-03, Vol.55 (3), p.737-746
Hauptverfasser:	Tang, Huadong, Radosz, Maciej, Shen, Youqing
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences atom transfer radical Catalysis Catalysts Catalytic reactions Chemical engineering Chemistry Copolymerization Copper Exact sciences and technology General and physical chemistry Ions living radical polymerization Molecular weight Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Reaction kinetics Reactors Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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