Chloroperoxidase halogenation reactions. Chemical versus enzymic halogenating intermediates

In the absence of organic substrates, chloroperoxidase catalyzes the peroxidation of chloride and bromide ion to molecular chlorine and bromine. However, these molecular species are not formed as intermediates in the enzymic halogenation of organic halogen-acceptor substrates. The rate of oxidation...

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Veröffentlicht in:	The Journal of biological chemistry 1982-05, Vol.257 (9), p.5030-5037
Hauptverfasser:	Libby, R D, Thomas, J A, Kaiser, L W, Hager, L P
Format:	Artikel
Sprache:	eng
Schlagworte:	Chloride Peroxidase - metabolism Chromatography, High Pressure Liquid Cyclohexanones Kinetics Methionine Peroxidases - metabolism Plants - enzymology Spectrophotometry, Ultraviolet
Online-Zugang:	Volltext
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