Lanthanide-Sensitized Lanthanide Luminescence: Terbium-Sensitized Ytterbium Luminescence in a Trinuclear Complex
A heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site...
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| Veröffentlicht in: | Journal of the American Chemical Society 2003-09, Vol.125 (35), p.10526-10527 |
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| container_end_page | 10527 |
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| container_issue | 35 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 125 |
| creator | Faulkner, Stephen Pope, Simon J. A |
| description | A heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site throughout the synthesis, while the ytterbium occupies the eight-coordinate site. Pumping the 488 nm absorption band of the terbium ion results in energy transfer to ytterbium with emission at 980 nm. |
| doi_str_mv | 10.1021/ja035634v |
| format | Article |
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A</creatorcontrib><title>Lanthanide-Sensitized Lanthanide Luminescence: Terbium-Sensitized Ytterbium Luminescence in a Trinuclear Complex</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>A heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site throughout the synthesis, while the ytterbium occupies the eight-coordinate site. Pumping the 488 nm absorption band of the terbium ion results in energy transfer to ytterbium with emission at 980 nm.</description><subject>Atomic and molecular physics</subject><subject>Chelating Agents - chemistry</subject><subject>Exact sciences and technology</subject><subject>Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)</subject><subject>Luminescent Measurements</subject><subject>Molecular properties and interactions with photons</subject><subject>Organometallic Compounds - chemistry</subject><subject>Pentetic Acid - analogs & derivatives</subject><subject>Physics</subject><subject>Radiationless transitions, quenching</subject><subject>Spectroscopy, Near-Infrared</subject><subject>Terbium - chemistry</subject><subject>Ytterbium - chemistry</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0MFu1DAQBmCrArVL4dAXQLmA1EOo7Ti2ww1WpSBWgNRw6MmaJGPhJXG2doIKp177mn0SjHbVBYmT5ZlPo18_ISeMvmKUs7M10KKUhfhxQBas5DQvGZePyIJSynOlZXFEnsS4Tl_BNTskR4xXgiquFySuwE_fwLsO80v00U3uF3bZfpqt5sF5jC36Fl_f395lNYbGzcPf_GqatsN_dOZ8BlkdnJ_bHiFky3HY9HjzlDy20Ed8tnuPydd35_Xyfb76fPFh-WaVgxDllGNpC4UoBVorik5orjrLkGvZCKC0YtZyzbtKaoGiTZQ1oEA3zDKqqtTHMXm5vbsJ4_WMcTKDS8n6HjyOczSqkLQqK53g6Ra2YYwxoDWb4AYIPw2j5k_D5qHhZJ_vjs7NgN1e7ipN4MUOQGyhtwF86-LelSm51Cq5fOtcnPDmYQ_hu5GqUKWpv1wa_umj0tVFbd7u70IbzXqcg0_d_Sfgb9NOoM4</recordid><startdate>20030903</startdate><enddate>20030903</enddate><creator>Faulkner, Stephen</creator><creator>Pope, Simon J. 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A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a445t-e5f37ee64eff43d4827df1e286b4a0091ff282d9684e4c37e1ba7a8b1f1079563</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Atomic and molecular physics</topic><topic>Chelating Agents - chemistry</topic><topic>Exact sciences and technology</topic><topic>Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)</topic><topic>Luminescent Measurements</topic><topic>Molecular properties and interactions with photons</topic><topic>Organometallic Compounds - chemistry</topic><topic>Pentetic Acid - analogs & derivatives</topic><topic>Physics</topic><topic>Radiationless transitions, quenching</topic><topic>Spectroscopy, Near-Infrared</topic><topic>Terbium - chemistry</topic><topic>Ytterbium - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Faulkner, Stephen</creatorcontrib><creatorcontrib>Pope, Simon J. A</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Faulkner, Stephen</au><au>Pope, Simon J. A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lanthanide-Sensitized Lanthanide Luminescence: Terbium-Sensitized Ytterbium Luminescence in a Trinuclear Complex</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2003-09-03</date><risdate>2003</risdate><volume>125</volume><issue>35</issue><spage>10526</spage><epage>10527</epage><pages>10526-10527</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>A heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site throughout the synthesis, while the ytterbium occupies the eight-coordinate site. Pumping the 488 nm absorption band of the terbium ion results in energy transfer to ytterbium with emission at 980 nm.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>12940728</pmid><doi>10.1021/ja035634v</doi><tpages>2</tpages></addata></record> |
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| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 2003-09, Vol.125 (35), p.10526-10527 |
| issn | 0002-7863 1520-5126 |
| language | eng |
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| source | MEDLINE; ACS Publications |
| subjects | Atomic and molecular physics Chelating Agents - chemistry Exact sciences and technology Fluorescence and phosphorescence radiationless transitions, quenching (intersystem crossing, internal conversion) Luminescent Measurements Molecular properties and interactions with photons Organometallic Compounds - chemistry Pentetic Acid - analogs & derivatives Physics Radiationless transitions, quenching Spectroscopy, Near-Infrared Terbium - chemistry Ytterbium - chemistry |
| title | Lanthanide-Sensitized Lanthanide Luminescence: Terbium-Sensitized Ytterbium Luminescence in a Trinuclear Complex |
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