Molecular Squares with Paramagnetic Diruthenium Corners:  Synthetic and Crystallographic Challenges

The reaction of Ru2(μ-O2CMe)4Cl with ∼2.5 equiv of HDAniF (HDAniF = N,N‘-di(p-anisyl)formamidine) in refluxing THF resulted in the synthesis of cis-Ru2(μ-DAniF)2(μ-O2CMe)2Cl (1). This Ru2 5+complex, which has two labile acetate groups occupying two equatorial cisoid positions, was used for the const...

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Veröffentlicht in:	Journal of the American Chemical Society 2003-08, Vol.125 (34), p.10327-10334
Hauptverfasser:	Angaridis, Panagiotis, Berry, John F, Cotton, F. Albert, Murillo, Carlos A, Wang, Xiaoping
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids
Online-Zugang:	Volltext
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