Hierarchical Assembly of Two-Dimensional Homochiral Nanocavity Arrays

Hierarchical Assembly of Two-Dimensional Homochiral Nanocavity Arrays

We demonstrate the rational design of nanoporous two-dimensional supramolecular structures by the hierarchical assembly of organic molecules and transition metal atoms at surfaces. Single-molecule level observations with scanning tunneling microscopy monitor the successive aufbau of structures with...

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Veröffentlicht in:Journal of the American Chemical Society 2003-09, Vol.125 (35), p.10725-10728
Hauptverfasser: Spillmann, Hannes, Dmitriev, Alexandre, Lin, Nian, Messina, Paolo, Barth, Johannes V, Kern, Klaus
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Sprache:eng
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Adsorption and desorption kinetics
evaporation and condensation
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Solid-fluid interfaces
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
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container_end_page 10728
container_issue 35
container_start_page 10725
container_title Journal of the American Chemical Society
container_volume 125
creator Spillmann, Hannes
Dmitriev, Alexandre
Lin, Nian
Messina, Paolo
Barth, Johannes V
Kern, Klaus
description We demonstrate the rational design of nanoporous two-dimensional supramolecular structures by the hierarchical assembly of organic molecules and transition metal atoms at surfaces. Single-molecule level observations with scanning tunneling microscopy monitor the successive aufbau of structures with increasing complexity. From the primary components secondary mononuclear chiral complexes are formed, which represent antecedents for tertiary polynuclear metal−organic nanogrids. These nanogrids represent the constituents of the eventually evolving two-dimensional networks comprising homochiral nanocavity arrays. Our findings visualize the evolution of complex matter in an exemplary way:  from per se achiral species via chiral intermediates to mesoscale dissymmetric structures.
doi_str_mv 10.1021/ja0362353
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source American Chemical Society Journals
subjects Adsorption and desorption kinetics
evaporation and condensation
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Solid-fluid interfaces
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
title Hierarchical Assembly of Two-Dimensional Homochiral Nanocavity Arrays
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