Palladium catalysed [2 + 2 + 1] intramolecular cycloaddition for the preparation of bicyclo[3.3.0]octa-1.5-dien-3-ones from 1,6-diynes

Palladium catalysed [2 + 2 + 1] cycloaddition of 1,6-heptadiynes with CO (1 atm) furnishes bicyclo[3.3.0]octa-1,5-dien-3-ones in 30-74% yield.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-08 (15), p.1902-1903
Hauptverfasser: Grigg, Ronald, Zhang, Lixin, Collard, Simon, Keep, Ann
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container_end_page 1903
container_issue 15
container_start_page 1902
container_title Chemical communications (Cambridge, England)
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creator Grigg, Ronald
Zhang, Lixin
Collard, Simon
Keep, Ann
description Palladium catalysed [2 + 2 + 1] cycloaddition of 1,6-heptadiynes with CO (1 atm) furnishes bicyclo[3.3.0]octa-1,5-dien-3-ones in 30-74% yield.
doi_str_mv 10.1039/b302841k
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source Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Palladium catalysed [2 + 2 + 1] intramolecular cycloaddition for the preparation of bicyclo[3.3.0]octa-1.5-dien-3-ones from 1,6-diynes
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