Synthesis and Magnetic Properties of a Metallacryptate that Behaves as a Single-Molecule Magnet
Crypt analysis: The reaction of manganese(II) chloride with sodium hydroxide, di‐(2‐pyridyl)‐ketonoxime, and sodium azide yields a metallacryptate consisting of 26 manganese centers, namely, four MnII (see picture; gold spheres) and 22 MnIII ions (green, aqua, and blue spheres). Results obtained fro...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2003-08, Vol.42 (32), p.3763-3766 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Dendrinou-Samara, Catherine Alexiou, Maria Zaleski, Curtis M. Kampf, Jeff W. Kirk, Martin L. Kessissoglou, Dimitris P. Pecoraro, Vincent L. |
| description | Crypt analysis: The reaction of manganese(II) chloride with sodium hydroxide, di‐(2‐pyridyl)‐ketonoxime, and sodium azide yields a metallacryptate consisting of 26 manganese centers, namely, four MnII (see picture; gold spheres) and 22 MnIII ions (green, aqua, and blue spheres). Results obtained from ac SQUID magnetic studies indicate that this molecule displays single‐molecule magnetic behavior. |
| doi_str_mv | 10.1002/anie.200351246 |
| format | Article |
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| subjects | Crystallization Crystallography, X-Ray Indicators and Reagents magnetic properties Magnetics manganese Manganese - chemistry metal-metal interactions metallacycles Models, Molecular Molecular Conformation Organometallic Compounds - chemical synthesis single-molecule studies Temperature |
| title | Synthesis and Magnetic Properties of a Metallacryptate that Behaves as a Single-Molecule Magnet |
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