New Strategic Reactions for Organic Synthesis:  Catalytic Asymmetric C−H Activation α to Oxygen as a Surrogate to the Aldol Reaction

The C−H activation of silyl ethers by means of rhodium carbenoid-induced C−H insertion represents a very direct method for the stereoselective synthesis of silyl-protected β-hydroxy esters. The reaction can proceed with very high regio-, diastereo-, and enantioselectivity and represents a surrogate...

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Veröffentlicht in:	Journal of organic chemistry 2003-08, Vol.68 (16), p.6126-6132
Hauptverfasser:	Davies, Huw M. L, Beckwith, Rohan E. J, Antoulinakis, Evan G, Jin, Qihui
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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