Regio- and Enantioselective Synthesis of Allylic Fluorides by Electrophilic Fluorodesilylation of Allyl Silanes

Enantiopure N‐fluorocinchona alkaloids promoted the electrophilic fluorodesilylation of allyl silanes in a conceptually new approach to the regio‐ and enantioselective formation of allylic fluorides (see scheme). Excellent conversions were observed in these reactions, which afforded the desired ally...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2003-07, Vol.42 (28), p.3291-3294
Hauptverfasser:	Greedy, Benjamin, Paris, Jean-Marc, Vidal, Thierry, Gouverneur, Véronique
Format:	Artikel
Sprache:	eng
Schlagworte:	allylic compounds asymmetric synthesis cinchona alkaloids fluorides silanes
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!