De Novo Asymmetric Bio- and Chemocatalytic Synthesis of Saccharides − Stereoselective Formal O-Glycoside Bond Formation Using Palladium Catalysis

A novel integrated bio- and chemocatalytic approach to the de novo catalytic asymmetric synthesis of saccharides has been developed. Acetoxypyranones obtained enantiopure by enzymatic resolution have been shown to undergo highly stereoselective palladium-catalyzed formal O-glycoside bond formation....

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Veröffentlicht in:	Journal of the American Chemical Society 2003-07, Vol.125 (29), p.8714-8715
Hauptverfasser:	Comely, Alex C, Eelkema, Rienk, Minnaard, Adriaan J, Feringa, Ben L
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetals - chemistry Carbohydrates - chemical synthesis Carbohydrates - chemistry Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Catalysis Chemistry Exact sciences and technology Glycosides - chemical synthesis Glycosides - chemistry Organic chemistry Palladium - chemistry Preparations and properties Pyrans - chemistry Stereoisomerism
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