Binuclear Manganese Compounds of Potential Biological Significance. Part 2. Mechanistic Study of Hydrogen Peroxide Disproportionation by Dimanganese Complexes:  The Two Oxygen Atoms of the Peroxide End up in a Dioxo Intermediate

The dimanganese(II,II) complexes 1a [Mn2(L)(OAc)2(CH3OH)](ClO4) and 1b [Mn2(L)(OBz)2(H2O)](ClO4), where HL is the unsymmetrical phenol ligand 2-(bis-(2-pyridylmethyl)aminomethyl)-6-((2-pyridylmethyl)(benzyl)aminomethyl)-4-methylphenol, react with hydrogen peroxide in acetonitrile solution. The dispr...

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Veröffentlicht in:	Inorganic chemistry 2003-08, Vol.42 (16), p.4817-4827
Hauptverfasser:	Dubois, Lionel, Caspar, Régis, Jacquamet, Lilian, Petit, Pierre-Emmanuel, Charlot, Marie-France, Baffert, Carole, Collomb, Marie-Noëlle, Deronzier, Alain, Latour, Jean-Marc
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Hydrogen Peroxide - chemistry Hydrogen-Ion Concentration Indicators and Reagents Ligands Manganese - chemistry Manganese Compounds - chemical synthesis Manganese Compounds - chemistry Oxides - chemical synthesis Oxides - chemistry Oxygen - chemistry Peroxides - chemistry Spectrometry, Mass, Electrospray Ionization Spectrophotometry, Ultraviolet
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