Terahertz Absorption Spectroscopy of a Liquid Using a Polarity Probe: A Case Study of Trehalose/Water Mixtures

The fluorescence relaxation of N‐methyl‐6‐quinolone was used to determine the frequency‐dependent permittivity of the molecular environment over a large spectral range (see picture), for example in trehalose–water solution. Local THz‐FIR spectroscopy can be realized by covalent attachment of the pro...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-01, Vol.49 (2), p.454-457
Hauptverfasser: Sajadi, Mohsen, Ajaj, Yathrib, Ioffe, Ilya, Weingärtner, Hermann, Ernsting, Nikolaus P
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container_issue 2
container_start_page 454
container_title Angewandte Chemie (International ed.)
container_volume 49
creator Sajadi, Mohsen
Ajaj, Yathrib
Ioffe, Ilya
Weingärtner, Hermann
Ernsting, Nikolaus P
description The fluorescence relaxation of N‐methyl‐6‐quinolone was used to determine the frequency‐dependent permittivity of the molecular environment over a large spectral range (see picture), for example in trehalose–water solution. Local THz‐FIR spectroscopy can be realized by covalent attachment of the probe molecule to a supramolecular structure.
doi_str_mv 10.1002/anie.200904997
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subjects Adsorption
Algorithms
fluorescence
Fluorescent Dyes
Indicators and Reagents
Protein Folding
Quinaldines - chemistry
Spectrometry, Fluorescence
terahertz spectroscopy
Terahertz Spectroscopy - methods
time-resolved Stokes shift
trehalose
Trehalose - chemistry
water
Water - chemistry
title Terahertz Absorption Spectroscopy of a Liquid Using a Polarity Probe: A Case Study of Trehalose/Water Mixtures
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