Pimelotides A and B, Diterpenoid Ketal-Lactone Orthoesters with an Unprecedented Skeleton from Pimelea elongata
A detailed investigation of the minor phytochemical components of Pimelea elongata foliage led to the discovery of two new diterpenoid daphnane ketal-lactone orthoesters with an unprecedented skeleton, pimelotides A (1) and B (2). Their structures and relative configurations were elucidated by NMR s...
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Veröffentlicht in: | Journal of natural products (Washington, D.C.) D.C.), 2009-12, Vol.72 (12), p.2081-2083 |
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creator | Hayes, Patricia Y Chow, Sharon Somerville, Michael J De Voss, James J Fletcher, Mary T |
description | A detailed investigation of the minor phytochemical components of Pimelea elongata foliage led to the discovery of two new diterpenoid daphnane ketal-lactone orthoesters with an unprecedented skeleton, pimelotides A (1) and B (2). Their structures and relative configurations were elucidated by NMR spectroscopy. |
doi_str_mv | 10.1021/np900573k |
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Psychology</subject><subject>Lactones - chemistry</subject><subject>Lactones - isolation & purification</subject><subject>Molecular Structure</subject><subject>Nuclear Magnetic Resonance, Biomolecular</subject><subject>Plant physiology and development</subject><subject>Thymelaeaceae - chemistry</subject><issn>0163-3864</issn><issn>1520-6025</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0MtuFDEQBVALgcgksOAHwBuEkGgoP_rhZUh4iZGCFGbdqnGXk0667Y7tEeLvMcwo2bDywsfXVZexFwLeC5Dig18MQN2q20dsJWoJVQOyfsxWIBpVqa7RR-w4pRsAUGDqp-xIGNN00qgVCz_GmaaQx4ESP-XoB_7xHT8fM8WFfBgH_p0yTtUabQ6e-EXM14FSuU7815ivywu-8UskSwP5TAO_vKWJiuUuhpn_iyfk5Q9_hRmfsScOp0TPD-cJ23z-9PPsa7W--PLt7HRdoWq6XHVWOF07bJzSpqzmWmkcCDU4rcXQdsY5h844ErLVVm6hU-1WEyCAE1QrdcLe7HOXGO52ZeB-HpOlaUJPYZf6VmkpatGaIt_upY0hpUiuX-I4Y_zdC-j_1tvf11vsy0PqbjvT8CAPfRbw-gAwWZxcRG_HdO-klI3Wuivu1d45DD1exWI2l7IsCKLTAFo8JKFN_U3YRV_q-s9IfwBF15eq</recordid><startdate>20091228</startdate><enddate>20091228</enddate><creator>Hayes, Patricia Y</creator><creator>Chow, Sharon</creator><creator>Somerville, Michael J</creator><creator>De Voss, James J</creator><creator>Fletcher, Mary T</creator><general>American Chemical Society and American Society of Pharmacognosy</general><general>American Society of Pharmacognosy</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20091228</creationdate><title>Pimelotides A and B, Diterpenoid Ketal-Lactone Orthoesters with an Unprecedented Skeleton from Pimelea elongata</title><author>Hayes, Patricia Y ; Chow, Sharon ; Somerville, Michael J ; De Voss, James J ; Fletcher, Mary T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a368t-8c1f45fa6f349057f729f013df441d789fffaf9fe1274c2b0837b4e0a00f1e533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Australia</topic><topic>Biological and medical sciences</topic><topic>Chemical constitution</topic><topic>Diterpenes - chemistry</topic><topic>Diterpenes - isolation & purification</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Lactones - chemistry</topic><topic>Lactones - isolation & purification</topic><topic>Molecular Structure</topic><topic>Nuclear Magnetic Resonance, Biomolecular</topic><topic>Plant physiology and development</topic><topic>Thymelaeaceae - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hayes, Patricia Y</creatorcontrib><creatorcontrib>Chow, Sharon</creatorcontrib><creatorcontrib>Somerville, Michael J</creatorcontrib><creatorcontrib>De Voss, James J</creatorcontrib><creatorcontrib>Fletcher, Mary T</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of natural products (Washington, D.C.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hayes, Patricia Y</au><au>Chow, Sharon</au><au>Somerville, Michael J</au><au>De Voss, James J</au><au>Fletcher, Mary T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pimelotides A and B, Diterpenoid Ketal-Lactone Orthoesters with an Unprecedented Skeleton from Pimelea elongata</atitle><jtitle>Journal of natural products (Washington, D.C.)</jtitle><addtitle>J. Nat. Prod</addtitle><date>2009-12-28</date><risdate>2009</risdate><volume>72</volume><issue>12</issue><spage>2081</spage><epage>2083</epage><pages>2081-2083</pages><issn>0163-3864</issn><eissn>1520-6025</eissn><coden>JNPRDF</coden><abstract>A detailed investigation of the minor phytochemical components of Pimelea elongata foliage led to the discovery of two new diterpenoid daphnane ketal-lactone orthoesters with an unprecedented skeleton, pimelotides A (1) and B (2). Their structures and relative configurations were elucidated by NMR spectroscopy.</abstract><cop>Northbrook, IL</cop><pub>American Chemical Society and American Society of Pharmacognosy</pub><pmid>19968293</pmid><doi>10.1021/np900573k</doi><tpages>3</tpages></addata></record> |
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source | MEDLINE; American Chemical Society Journals |
subjects | Australia Biological and medical sciences Chemical constitution Diterpenes - chemistry Diterpenes - isolation & purification Fundamental and applied biological sciences. Psychology Lactones - chemistry Lactones - isolation & purification Molecular Structure Nuclear Magnetic Resonance, Biomolecular Plant physiology and development Thymelaeaceae - chemistry |
title | Pimelotides A and B, Diterpenoid Ketal-Lactone Orthoesters with an Unprecedented Skeleton from Pimelea elongata |
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