The influence of halogen substituents on the course of hydrogallation and hydroalumination reactions

Treatment of trimethylsilylethynylbenzene derivatives with HGaCl(2) afforded products, [C(6)H(6-x){C(H)=C(SiMe(3))GaCl(2)}(x)], in which by a very fast cis/trans-rearrangement the Ga and H atoms occupied opposite sides of the resulting C=C double bonds. The stability of the cis-forms considerably in...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2009-01 (47), p.10550-10562
Hauptverfasser:	Uhl, Werner, Claesener, Michael, Hepp, Alexander, Jasper, Beate, Vinogradov, Andrej, van Wüllen, Leo, Köster, Thomas K-J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!