Photo-Thermal Haptotropism in Cyclopentadienylcobalt Complexes of Linear Phenylenes: Intercyclobutadiene Metal Migration

The CpCo‐shuffle: {CpCo} complexes of linear [3]‐ and [5]phenylene undergo a light‐induced haptotropic migration from a more strongly bound cyclobutadiene moiety to a less strongly bound (see scheme). The shift is thermally reversible and proceeds along the periphery of the intervening arene rings....

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Veröffentlicht in:	Angewandte Chemie International Edition 2009-01, Vol.48 (52), p.9853-9857
Hauptverfasser:	Albright, Thomas A., Dosa, Peter I., Grossmann, Tom N., Khrustalev, Victor N., Oloba, Oluwakemi A., Padilla, Robin, Paubelle, Renaud, Stanger, Amnon, Timofeeva, Tatiana V., Vollhardt, K. Peter C.
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Sprache:	eng
Schlagworte:	ab initio calculations arene ligands haptotropism isomerization photochemistry
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creator	Albright, Thomas A. Dosa, Peter I. Grossmann, Tom N. Khrustalev, Victor N. Oloba, Oluwakemi A. Padilla, Robin Paubelle, Renaud Stanger, Amnon Timofeeva, Tatiana V. Vollhardt, K. Peter C.
description	The CpCo‐shuffle: {CpCo} complexes of linear [3]‐ and [5]phenylene undergo a light‐induced haptotropic migration from a more strongly bound cyclobutadiene moiety to a less strongly bound (see scheme). The shift is thermally reversible and proceeds along the periphery of the intervening arene rings. As such, the systems constitute photo–thermal storage systems, as well the first examples of cyclobutadiene‐to‐cyclobutadiene haptotropism.
doi_str_mv	10.1002/anie.200905088
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subjects	ab initio calculations arene ligands haptotropism isomerization photochemistry
title	Photo-Thermal Haptotropism in Cyclopentadienylcobalt Complexes of Linear Phenylenes: Intercyclobutadiene Metal Migration
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