Direct Evidence of High Spatial Localization of Hot Spots in Surface-Enhanced Raman Scattering

Hot and cold: The high degree of localization in SERS hot spots is demonstrated directly by a selective deposition of Raman analytes inside and outside the field‐enhanced regions in a plasmonic cavity (see picture). The localization is demonstrated by measurements of both the absolute SERS intensiti...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-12, Vol.48 (52), p.9932-9935
Hauptverfasser: Chen, Chang, Hutchison, James Andell, Clemente, Francesca, Kox, Ronald, Uji-I, Hiroshi, Hofkens, Johan, Lagae, Liesbet, Maes, Guido, Borghs, Gustaaf, Van Dorpe, Pol
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Sprache:eng
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Zusammenfassung:Hot and cold: The high degree of localization in SERS hot spots is demonstrated directly by a selective deposition of Raman analytes inside and outside the field‐enhanced regions in a plasmonic cavity (see picture). The localization is demonstrated by measurements of both the absolute SERS intensities and the kinetics for photoinduced degradation at different positions.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200905389