An abundant chlorinated furanone in the spent chlorination liquor from pulp bleaching
Gas chromatography with electron capture detection of acetylated spent liquors from the bleaching of chemical pulp showed a large peak attributed to an unknown compound. The same peak was present in the analysis of chlorinated naturally occurring humic acid. GC multistage mass spectrometry, proton n...
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| Veröffentlicht in: | Environ. Sci. Technol.; (United States) 1987-08, Vol.21 (8), p.754-756 |
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| container_title | Environ. Sci. Technol.; (United States) |
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| creator | Stroemberg, Lars M De Sousa, Filipe Ljungquist, Pierre McKague, Bruce Kringstad, Knut P |
| description | Gas chromatography with electron capture detection of acetylated spent liquors from the bleaching of chemical pulp showed a large peak attributed to an unknown compound. The same peak was present in the analysis of chlorinated naturally occurring humic acid. GC multistage mass spectrometry, proton nmr, carbon-13 nmr, UV and IR spectroscopy showed the compound to be 3,4-dichloro-5-(dichloromethyl)-5-hydroxy-2-furanone. The unacetylated furanone exhibited weak mutagenic activity in the Ames test using Salmonella typhimurium TA100. It also showed a slightly elevated propensity to bioaccumulation and was chemically unstable. |
| doi_str_mv | 10.1021/es00162a004 |
| format | Article |
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The same peak was present in the analysis of chlorinated naturally occurring humic acid. GC multistage mass spectrometry, proton nmr, carbon-13 nmr, UV and IR spectroscopy showed the compound to be 3,4-dichloro-5-(dichloromethyl)-5-hydroxy-2-furanone. The unacetylated furanone exhibited weak mutagenic activity in the Ames test using Salmonella typhimurium TA100. 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POLLUTANT EFFECTS ON LIVING ORGS. AND BIOL. MAT ; SCREENING ; SEPARATION PROCESSES ; SPENT LIQUORS ; SPIRITS ; WASTES ; WATER POLLUTION ; WOOD ; Wood. Paper. Non wovens</subject><ispartof>Environ. Sci. 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Sci. Technol.; (United States)</title><addtitle>Environ. Sci. Technol</addtitle><description>Gas chromatography with electron capture detection of acetylated spent liquors from the bleaching of chemical pulp showed a large peak attributed to an unknown compound. The same peak was present in the analysis of chlorinated naturally occurring humic acid. GC multistage mass spectrometry, proton nmr, carbon-13 nmr, UV and IR spectroscopy showed the compound to be 3,4-dichloro-5-(dichloromethyl)-5-hydroxy-2-furanone. The unacetylated furanone exhibited weak mutagenic activity in the Ames test using Salmonella typhimurium TA100. It also showed a slightly elevated propensity to bioaccumulation and was chemically unstable.</description><subject>560300 - Chemicals Metabolism & Toxicology</subject><subject>AGUARDIENTES</subject><subject>Applied sciences</subject><subject>AROMATICS</subject><subject>BIOLOGICAL ACCUMULATION</subject><subject>BLANCHISSEMENT</subject><subject>BLEACHING</subject><subject>CAPTURE</subject><subject>CHEMICAL COMPOSITION</subject><subject>CHEMICAL PROPERTIES</subject><subject>CHEMICAL REACTIONS</subject><subject>CHLORE</subject><subject>CHLORINATED AROMATIC HYDROCARBONS</subject><subject>CHLORINATION</subject><subject>CHLORINE</subject><subject>CHROMATOGRAPHIE EN PHASE GAZEUSE</subject><subject>CHROMATOGRAPHY</subject><subject>CLORO</subject><subject>COMPOSE PHENOLIQUE</subject><subject>COMPUESTOS FENOLICOS</subject><subject>CONTAMINACION DEL AGUA</subject><subject>CROMATOGRAFIA DE GASES</subject><subject>DECHET LIQUIDE</subject><subject>DECOLORACION</subject><subject>DESECHOS LIQUIDOS</subject><subject>EAU DE VIE</subject><subject>ELECTRON CAPTURE</subject><subject>Exact sciences and technology</subject><subject>GAS CHROMATOGRAPHY</subject><subject>HALOGENATED AROMATIC HYDROCARBONS</subject><subject>HALOGENATION</subject><subject>INDUSTRIAL WASTES</subject><subject>LIQUID WASTES</subject><subject>MUTAGEN SCREENING</subject><subject>ORGANIC CHLORINE COMPOUNDS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>Paper, paperboard, non wovens</subject><subject>PATE CELLULOSIQUE</subject><subject>PHENOLIC COMPOUNDS</subject><subject>POLLUTION DE L'EAU</subject><subject>Polymer industry, paints, wood</subject><subject>PULP</subject><subject>PULPA</subject><subject>RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTANT EFFECTS ON LIVING ORGS. AND BIOL. MAT</subject><subject>SCREENING</subject><subject>SEPARATION PROCESSES</subject><subject>SPENT LIQUORS</subject><subject>SPIRITS</subject><subject>WASTES</subject><subject>WATER POLLUTION</subject><subject>WOOD</subject><subject>Wood. Paper. Non wovens</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNqN0sFrFDEUBvBBFFurJ68ig4geZPQlmUxejnWxKlRU2oXeQpLJdFNnk20yA_rfm7JL24PYngLJjy_k5auq5wTeE6Dkg8sApKMaoH1Q7RNOoeHIycNqv-yzRrLubK96kvMFAFAG-LjaI1JKDlzsV8vDUGszh16HqbarMSYf9OT6epiTDjG42od6Wrk6b9xt4WOoR385x1QPKa7rzTxuajM6bVc-nD-tHg16zO7Zbj2olkefThdfmuPvn78uDo8bzRGnhgoukLY9sg6McdqA5mbAATnroTeEGGYYdIMlkhkOlg-MITLLO0q6niE7qF5tc2OevMrWT86ubAzB2UlxQmWRBb3dok2Kl7PLk1r7bN046uDinJVgLRG87XiRb_4rqUSgSOU9IJNI4G5IWkFQ4H0gJW2Zxd2QCRQSoMB3W2hTzDm5QW2SX-v0RxFQV8VRt4pT9Mtd7GzWrr-xu6YU8HoHdLZ6HEo7rM_XTnBKgFzd2myZz5P7fX2s0y_VCSa4Ov1xonBx9vPjUUvVt-JfbP2go9LnqUQuT7CkcYmIN3-nbVYXcU6h1OmfD_gLiq_sMw</recordid><startdate>19870801</startdate><enddate>19870801</enddate><creator>Stroemberg, Lars M</creator><creator>De Sousa, Filipe</creator><creator>Ljungquist, Pierre</creator><creator>McKague, Bruce</creator><creator>Kringstad, Knut P</creator><general>American Chemical Society</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7TV</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>F28</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>19870801</creationdate><title>An abundant chlorinated furanone in the spent chlorination liquor from pulp bleaching</title><author>Stroemberg, Lars M ; De Sousa, Filipe ; Ljungquist, Pierre ; McKague, Bruce ; Kringstad, Knut P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a588t-2757824d8360bbeab0a5bf8f853d0db11b3b306fc193b50c5f33883c56216d383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>560300 - Chemicals Metabolism & Toxicology</topic><topic>AGUARDIENTES</topic><topic>Applied sciences</topic><topic>AROMATICS</topic><topic>BIOLOGICAL ACCUMULATION</topic><topic>BLANCHISSEMENT</topic><topic>BLEACHING</topic><topic>CAPTURE</topic><topic>CHEMICAL COMPOSITION</topic><topic>CHEMICAL PROPERTIES</topic><topic>CHEMICAL REACTIONS</topic><topic>CHLORE</topic><topic>CHLORINATED AROMATIC HYDROCARBONS</topic><topic>CHLORINATION</topic><topic>CHLORINE</topic><topic>CHROMATOGRAPHIE EN PHASE GAZEUSE</topic><topic>CHROMATOGRAPHY</topic><topic>CLORO</topic><topic>COMPOSE PHENOLIQUE</topic><topic>COMPUESTOS FENOLICOS</topic><topic>CONTAMINACION DEL AGUA</topic><topic>CROMATOGRAFIA DE GASES</topic><topic>DECHET LIQUIDE</topic><topic>DECOLORACION</topic><topic>DESECHOS LIQUIDOS</topic><topic>EAU DE VIE</topic><topic>ELECTRON CAPTURE</topic><topic>Exact sciences and technology</topic><topic>GAS CHROMATOGRAPHY</topic><topic>HALOGENATED AROMATIC HYDROCARBONS</topic><topic>HALOGENATION</topic><topic>INDUSTRIAL WASTES</topic><topic>LIQUID WASTES</topic><topic>MUTAGEN SCREENING</topic><topic>ORGANIC CHLORINE COMPOUNDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>Paper, paperboard, non wovens</topic><topic>PATE CELLULOSIQUE</topic><topic>PHENOLIC COMPOUNDS</topic><topic>POLLUTION DE L'EAU</topic><topic>Polymer industry, paints, wood</topic><topic>PULP</topic><topic>PULPA</topic><topic>RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTANT EFFECTS ON LIVING ORGS. AND BIOL. MAT</topic><topic>SCREENING</topic><topic>SEPARATION PROCESSES</topic><topic>SPENT LIQUORS</topic><topic>SPIRITS</topic><topic>WASTES</topic><topic>WATER POLLUTION</topic><topic>WOOD</topic><topic>Wood. Paper. Non wovens</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stroemberg, Lars M</creatorcontrib><creatorcontrib>De Sousa, Filipe</creatorcontrib><creatorcontrib>Ljungquist, Pierre</creatorcontrib><creatorcontrib>McKague, Bruce</creatorcontrib><creatorcontrib>Kringstad, Knut P</creatorcontrib><creatorcontrib>STFI (Swedish Pulp and Paper Research Institute), Stockholm</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Pollution Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Environ. Sci. Technol.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stroemberg, Lars M</au><au>De Sousa, Filipe</au><au>Ljungquist, Pierre</au><au>McKague, Bruce</au><au>Kringstad, Knut P</au><aucorp>STFI (Swedish Pulp and Paper Research Institute), Stockholm</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An abundant chlorinated furanone in the spent chlorination liquor from pulp bleaching</atitle><jtitle>Environ. Sci. Technol.; (United States)</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>1987-08-01</date><risdate>1987</risdate><volume>21</volume><issue>8</issue><spage>754</spage><epage>756</epage><pages>754-756</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>Gas chromatography with electron capture detection of acetylated spent liquors from the bleaching of chemical pulp showed a large peak attributed to an unknown compound. The same peak was present in the analysis of chlorinated naturally occurring humic acid. GC multistage mass spectrometry, proton nmr, carbon-13 nmr, UV and IR spectroscopy showed the compound to be 3,4-dichloro-5-(dichloromethyl)-5-hydroxy-2-furanone. The unacetylated furanone exhibited weak mutagenic activity in the Ames test using Salmonella typhimurium TA100. It also showed a slightly elevated propensity to bioaccumulation and was chemically unstable.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>19995057</pmid><doi>10.1021/es00162a004</doi><tpages>3</tpages></addata></record> |
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| identifier | ISSN: 0013-936X |
| ispartof | Environ. Sci. Technol.; (United States), 1987-08, Vol.21 (8), p.754-756 |
| issn | 0013-936X 1520-5851 |
| language | eng |
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| source | ACS Publications |
| subjects | 560300 - Chemicals Metabolism & Toxicology AGUARDIENTES Applied sciences AROMATICS BIOLOGICAL ACCUMULATION BLANCHISSEMENT BLEACHING CAPTURE CHEMICAL COMPOSITION CHEMICAL PROPERTIES CHEMICAL REACTIONS CHLORE CHLORINATED AROMATIC HYDROCARBONS CHLORINATION CHLORINE CHROMATOGRAPHIE EN PHASE GAZEUSE CHROMATOGRAPHY CLORO COMPOSE PHENOLIQUE COMPUESTOS FENOLICOS CONTAMINACION DEL AGUA CROMATOGRAFIA DE GASES DECHET LIQUIDE DECOLORACION DESECHOS LIQUIDOS EAU DE VIE ELECTRON CAPTURE Exact sciences and technology GAS CHROMATOGRAPHY HALOGENATED AROMATIC HYDROCARBONS HALOGENATION INDUSTRIAL WASTES LIQUID WASTES MUTAGEN SCREENING ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS Paper, paperboard, non wovens PATE CELLULOSIQUE PHENOLIC COMPOUNDS POLLUTION DE L'EAU Polymer industry, paints, wood PULP PULPA RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTANT EFFECTS ON LIVING ORGS. AND BIOL. MAT SCREENING SEPARATION PROCESSES SPENT LIQUORS SPIRITS WASTES WATER POLLUTION WOOD Wood. Paper. Non wovens |
| title | An abundant chlorinated furanone in the spent chlorination liquor from pulp bleaching |
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