Equilibrium, kinetic and thermodynamic studies on the biosorption of Cu(II) onto chestnut shell

The biosorption of Cu(II) onto chestnut shell, a residue of the food processing industry, in a batch adsorber has been studied. Equilibrium isotherms, kinetic data, and thermodynamic parameters have been evaluated. Equilibrium data agreed well with Langmuir isotherm and Redlich–Peterson isotherm mod...

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Veröffentlicht in:Journal of hazardous materials 2010-02, Vol.174 (1), p.137-143
Hauptverfasser: Yao, Z.-Y., Qi, J.-H., Wang, L.-H.
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Qi, J.-H.
Wang, L.-H.
description The biosorption of Cu(II) onto chestnut shell, a residue of the food processing industry, in a batch adsorber has been studied. Equilibrium isotherms, kinetic data, and thermodynamic parameters have been evaluated. Equilibrium data agreed well with Langmuir isotherm and Redlich–Peterson isotherm models. The adsorption capacity of chestnut shell for Cu(II) was determined with the Langmuir model and was found to be 12.56 mg g −1 at 293 K. The kinetic data were found to follow the pseudo-second-order model. Intra-particle diffusion is not the sole rate-controlling factor. Gibbs free energy was spontaneous for all interactions, and the adsorption process exhibited exothermic enthalpy values. Chestnut shell was shown to be a promising biosorbent for Cu(II) removal from aqueous solutions.
doi_str_mv 10.1016/j.jhazmat.2009.09.027
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subjects Adsorption
Applied sciences
Biological and medical sciences
Biosorption
Biotechnology
Chemical engineering
Chestnut shell
Copper
Copper - chemistry
Exact sciences and technology
Food engineering
Food industries
Food Industry
Fundamental and applied biological sciences. Psychology
General aspects
Hydrogen-Ion Concentration
Industrial Waste
Isotherm
Kinetics
Methods. Procedures. Technologies
Nuts
Others
Pollution
Spectroscopy, Fourier Transform Infrared
Thermodynamics
Various methods and equipments
title Equilibrium, kinetic and thermodynamic studies on the biosorption of Cu(II) onto chestnut shell
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