Equilibrium, kinetic and thermodynamic studies on the biosorption of Cu(II) onto chestnut shell
The biosorption of Cu(II) onto chestnut shell, a residue of the food processing industry, in a batch adsorber has been studied. Equilibrium isotherms, kinetic data, and thermodynamic parameters have been evaluated. Equilibrium data agreed well with Langmuir isotherm and Redlich–Peterson isotherm mod...
Gespeichert in:
Veröffentlicht in: | Journal of hazardous materials 2010-02, Vol.174 (1), p.137-143 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 143 |
---|---|
container_issue | 1 |
container_start_page | 137 |
container_title | Journal of hazardous materials |
container_volume | 174 |
creator | Yao, Z.-Y. Qi, J.-H. Wang, L.-H. |
description | The biosorption of Cu(II) onto chestnut shell, a residue of the food processing industry, in a batch adsorber has been studied. Equilibrium isotherms, kinetic data, and thermodynamic parameters have been evaluated. Equilibrium data agreed well with Langmuir isotherm and Redlich–Peterson isotherm models. The adsorption capacity of chestnut shell for Cu(II) was determined with the Langmuir model and was found to be 12.56
mg
g
−1 at 293
K. The kinetic data were found to follow the pseudo-second-order model. Intra-particle diffusion is not the sole rate-controlling factor. Gibbs free energy was spontaneous for all interactions, and the adsorption process exhibited exothermic enthalpy values. Chestnut shell was shown to be a promising biosorbent for Cu(II) removal from aqueous solutions. |
doi_str_mv | 10.1016/j.jhazmat.2009.09.027 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_734172393</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0304389409014733</els_id><sourcerecordid>734172393</sourcerecordid><originalsourceid>FETCH-LOGICAL-c394t-425bdbae228de5e45e62f90b5058a68172256a040bbcdee40b753d8038d40bb13</originalsourceid><addsrcrecordid>eNqFkE1r3DAQhkVJaDZpf0KLL6EJxFt92vKphCVJFwK9pGchS2NWW9vaSHIh_fWRWdMcAwOjmXlm9PIi9IXgNcGk-r5f73f636DTmmLcrOeg9Qe0IrJmJWOsOkErzDAvmWz4GTqPcY8xJrXgH9EZaWR-V80KqbvnyfWuDW4aboo_boTkTKFHW6QdhMHbl1EPuRPTZB3Ewo_zoGidjz4cksu174rNdLXdXudh8oXZQUzjlIq4g77_hE473Uf4vOQL9Pv-7mnzs3z89bDd3D6WhjU8lZyK1rYaKJUWBHABFe0a3AospK4kqSkVlcYct62xADnXglmJmbRzj7AL9O149xD885QVqMFFkwXoEfwUVc14PsIalklxJE3wMQbo1CG4QYcXRbCarVV7tVirZmvVHLTOe1-XH6Z2APu2tXiZgcsF0NHovgt6NC7-5yjNEoTkmftx5CD78ddBUNE4GA1YF8AkZb17R8orAKSabg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>734172393</pqid></control><display><type>article</type><title>Equilibrium, kinetic and thermodynamic studies on the biosorption of Cu(II) onto chestnut shell</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals</source><creator>Yao, Z.-Y. ; Qi, J.-H. ; Wang, L.-H.</creator><creatorcontrib>Yao, Z.-Y. ; Qi, J.-H. ; Wang, L.-H.</creatorcontrib><description>The biosorption of Cu(II) onto chestnut shell, a residue of the food processing industry, in a batch adsorber has been studied. Equilibrium isotherms, kinetic data, and thermodynamic parameters have been evaluated. Equilibrium data agreed well with Langmuir isotherm and Redlich–Peterson isotherm models. The adsorption capacity of chestnut shell for Cu(II) was determined with the Langmuir model and was found to be 12.56
mg
g
−1 at 293
K. The kinetic data were found to follow the pseudo-second-order model. Intra-particle diffusion is not the sole rate-controlling factor. Gibbs free energy was spontaneous for all interactions, and the adsorption process exhibited exothermic enthalpy values. Chestnut shell was shown to be a promising biosorbent for Cu(II) removal from aqueous solutions.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2009.09.027</identifier><identifier>PMID: 19800169</identifier><identifier>CODEN: JHMAD9</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Adsorption ; Applied sciences ; Biological and medical sciences ; Biosorption ; Biotechnology ; Chemical engineering ; Chestnut shell ; Copper ; Copper - chemistry ; Exact sciences and technology ; Food engineering ; Food industries ; Food Industry ; Fundamental and applied biological sciences. Psychology ; General aspects ; Hydrogen-Ion Concentration ; Industrial Waste ; Isotherm ; Kinetics ; Methods. Procedures. Technologies ; Nuts ; Others ; Pollution ; Spectroscopy, Fourier Transform Infrared ; Thermodynamics ; Various methods and equipments</subject><ispartof>Journal of hazardous materials, 2010-02, Vol.174 (1), p.137-143</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c394t-425bdbae228de5e45e62f90b5058a68172256a040bbcdee40b753d8038d40bb13</citedby><cites>FETCH-LOGICAL-c394t-425bdbae228de5e45e62f90b5058a68172256a040bbcdee40b753d8038d40bb13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0304389409014733$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22341584$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19800169$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yao, Z.-Y.</creatorcontrib><creatorcontrib>Qi, J.-H.</creatorcontrib><creatorcontrib>Wang, L.-H.</creatorcontrib><title>Equilibrium, kinetic and thermodynamic studies on the biosorption of Cu(II) onto chestnut shell</title><title>Journal of hazardous materials</title><addtitle>J Hazard Mater</addtitle><description>The biosorption of Cu(II) onto chestnut shell, a residue of the food processing industry, in a batch adsorber has been studied. Equilibrium isotherms, kinetic data, and thermodynamic parameters have been evaluated. Equilibrium data agreed well with Langmuir isotherm and Redlich–Peterson isotherm models. The adsorption capacity of chestnut shell for Cu(II) was determined with the Langmuir model and was found to be 12.56
mg
g
−1 at 293
K. The kinetic data were found to follow the pseudo-second-order model. Intra-particle diffusion is not the sole rate-controlling factor. Gibbs free energy was spontaneous for all interactions, and the adsorption process exhibited exothermic enthalpy values. Chestnut shell was shown to be a promising biosorbent for Cu(II) removal from aqueous solutions.</description><subject>Adsorption</subject><subject>Applied sciences</subject><subject>Biological and medical sciences</subject><subject>Biosorption</subject><subject>Biotechnology</subject><subject>Chemical engineering</subject><subject>Chestnut shell</subject><subject>Copper</subject><subject>Copper - chemistry</subject><subject>Exact sciences and technology</subject><subject>Food engineering</subject><subject>Food industries</subject><subject>Food Industry</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General aspects</subject><subject>Hydrogen-Ion Concentration</subject><subject>Industrial Waste</subject><subject>Isotherm</subject><subject>Kinetics</subject><subject>Methods. Procedures. Technologies</subject><subject>Nuts</subject><subject>Others</subject><subject>Pollution</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Thermodynamics</subject><subject>Various methods and equipments</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkE1r3DAQhkVJaDZpf0KLL6EJxFt92vKphCVJFwK9pGchS2NWW9vaSHIh_fWRWdMcAwOjmXlm9PIi9IXgNcGk-r5f73f636DTmmLcrOeg9Qe0IrJmJWOsOkErzDAvmWz4GTqPcY8xJrXgH9EZaWR-V80KqbvnyfWuDW4aboo_boTkTKFHW6QdhMHbl1EPuRPTZB3Ewo_zoGidjz4cksu174rNdLXdXudh8oXZQUzjlIq4g77_hE473Uf4vOQL9Pv-7mnzs3z89bDd3D6WhjU8lZyK1rYaKJUWBHABFe0a3AospK4kqSkVlcYct62xADnXglmJmbRzj7AL9O149xD885QVqMFFkwXoEfwUVc14PsIalklxJE3wMQbo1CG4QYcXRbCarVV7tVirZmvVHLTOe1-XH6Z2APu2tXiZgcsF0NHovgt6NC7-5yjNEoTkmftx5CD78ddBUNE4GA1YF8AkZb17R8orAKSabg</recordid><startdate>20100215</startdate><enddate>20100215</enddate><creator>Yao, Z.-Y.</creator><creator>Qi, J.-H.</creator><creator>Wang, L.-H.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20100215</creationdate><title>Equilibrium, kinetic and thermodynamic studies on the biosorption of Cu(II) onto chestnut shell</title><author>Yao, Z.-Y. ; Qi, J.-H. ; Wang, L.-H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c394t-425bdbae228de5e45e62f90b5058a68172256a040bbcdee40b753d8038d40bb13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Adsorption</topic><topic>Applied sciences</topic><topic>Biological and medical sciences</topic><topic>Biosorption</topic><topic>Biotechnology</topic><topic>Chemical engineering</topic><topic>Chestnut shell</topic><topic>Copper</topic><topic>Copper - chemistry</topic><topic>Exact sciences and technology</topic><topic>Food engineering</topic><topic>Food industries</topic><topic>Food Industry</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>General aspects</topic><topic>Hydrogen-Ion Concentration</topic><topic>Industrial Waste</topic><topic>Isotherm</topic><topic>Kinetics</topic><topic>Methods. Procedures. Technologies</topic><topic>Nuts</topic><topic>Others</topic><topic>Pollution</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Thermodynamics</topic><topic>Various methods and equipments</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yao, Z.-Y.</creatorcontrib><creatorcontrib>Qi, J.-H.</creatorcontrib><creatorcontrib>Wang, L.-H.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yao, Z.-Y.</au><au>Qi, J.-H.</au><au>Wang, L.-H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Equilibrium, kinetic and thermodynamic studies on the biosorption of Cu(II) onto chestnut shell</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2010-02-15</date><risdate>2010</risdate><volume>174</volume><issue>1</issue><spage>137</spage><epage>143</epage><pages>137-143</pages><issn>0304-3894</issn><eissn>1873-3336</eissn><coden>JHMAD9</coden><abstract>The biosorption of Cu(II) onto chestnut shell, a residue of the food processing industry, in a batch adsorber has been studied. Equilibrium isotherms, kinetic data, and thermodynamic parameters have been evaluated. Equilibrium data agreed well with Langmuir isotherm and Redlich–Peterson isotherm models. The adsorption capacity of chestnut shell for Cu(II) was determined with the Langmuir model and was found to be 12.56
mg
g
−1 at 293
K. The kinetic data were found to follow the pseudo-second-order model. Intra-particle diffusion is not the sole rate-controlling factor. Gibbs free energy was spontaneous for all interactions, and the adsorption process exhibited exothermic enthalpy values. Chestnut shell was shown to be a promising biosorbent for Cu(II) removal from aqueous solutions.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><pmid>19800169</pmid><doi>10.1016/j.jhazmat.2009.09.027</doi><tpages>7</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0304-3894 |
ispartof | Journal of hazardous materials, 2010-02, Vol.174 (1), p.137-143 |
issn | 0304-3894 1873-3336 |
language | eng |
recordid | cdi_proquest_miscellaneous_734172393 |
source | MEDLINE; Elsevier ScienceDirect Journals |
subjects | Adsorption Applied sciences Biological and medical sciences Biosorption Biotechnology Chemical engineering Chestnut shell Copper Copper - chemistry Exact sciences and technology Food engineering Food industries Food Industry Fundamental and applied biological sciences. Psychology General aspects Hydrogen-Ion Concentration Industrial Waste Isotherm Kinetics Methods. Procedures. Technologies Nuts Others Pollution Spectroscopy, Fourier Transform Infrared Thermodynamics Various methods and equipments |
title | Equilibrium, kinetic and thermodynamic studies on the biosorption of Cu(II) onto chestnut shell |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T22%3A15%3A45IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Equilibrium,%20kinetic%20and%20thermodynamic%20studies%20on%20the%20biosorption%20of%20Cu(II)%20onto%20chestnut%20shell&rft.jtitle=Journal%20of%20hazardous%20materials&rft.au=Yao,%20Z.-Y.&rft.date=2010-02-15&rft.volume=174&rft.issue=1&rft.spage=137&rft.epage=143&rft.pages=137-143&rft.issn=0304-3894&rft.eissn=1873-3336&rft.coden=JHMAD9&rft_id=info:doi/10.1016/j.jhazmat.2009.09.027&rft_dat=%3Cproquest_cross%3E734172393%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=734172393&rft_id=info:pmid/19800169&rft_els_id=S0304389409014733&rfr_iscdi=true |