A novel chelatofore functionalized spiropyran of the 2-oxaindane series

A novel chelatofore functionalized spiropyran of the 2‐oxaindane series, namely 8‐formyl‐7‐hydroxy‐3′,3′‐dimethylspiro[2H‐chromene‐2,1′(3′H)‐2‐benzofuran], C19H16O4, is reported. In the crystalline state, dimers are formed as a result of the π–π stacking of aromatic groups of the 2H‐chromene part of...

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Veröffentlicht in:	Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2009-12, Vol.65 (12), p.o618-o620
Hauptverfasser:	Bulanov, Antony O., Shcherbakov, Igor N., Tupolova, Yulia P., Popov, Leonid D., Lukov, Vladimir V., Kogan, Victor A., Belikov, Pavel A.
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Sprache:	eng
Schlagworte:	Chemical bonds Chemical compounds Crystal structure Crystallography Molecules
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container_title	Acta crystallographica. Section C, Crystal structure communications
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creator	Bulanov, Antony O. Shcherbakov, Igor N. Tupolova, Yulia P. Popov, Leonid D. Lukov, Vladimir V. Kogan, Victor A. Belikov, Pavel A.
description	A novel chelatofore functionalized spiropyran of the 2‐oxaindane series, namely 8‐formyl‐7‐hydroxy‐3′,3′‐dimethylspiro[2H‐chromene‐2,1′(3′H)‐2‐benzofuran], C19H16O4, is reported. In the crystalline state, dimers are formed as a result of the π–π stacking of aromatic groups of the 2H‐chromene part of the molecule and C—H...O interactions. The Cspiro—O bond length in the pyran ring is 1.4558 (10) Å, which is longer than or equal to the bond length in thermo‐ and photochromic 2‐oxaindane spiropyrans synthesized previously, except for the 7,8‐benzo/6‐NO2 derivative, in which this bond length is 1.465 (2) Å.
doi_str_mv	10.1107/S0108270109044771
format	Article
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C</addtitle><date>2009-12</date><risdate>2009</risdate><volume>65</volume><issue>12</issue><spage>o618</spage><epage>o620</epage><pages>o618-o620</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>A novel chelatofore functionalized spiropyran of the 2‐oxaindane series, namely 8‐formyl‐7‐hydroxy‐3′,3′‐dimethylspiro[2H‐chromene‐2,1′(3′H)‐2‐benzofuran], C19H16O4, is reported. In the crystalline state, dimers are formed as a result of the π–π stacking of aromatic groups of the 2H‐chromene part of the molecule and C—H...O interactions. The Cspiro—O bond length in the pyran ring is 1.4558 (10) Å, which is longer than or equal to the bond length in thermo‐ and photochromic 2‐oxaindane spiropyrans synthesized previously, except for the 7,8‐benzo/6‐NO2 derivative, in which this bond length is 1.465 (2) Å.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><pmid>19966444</pmid><doi>10.1107/S0108270109044771</doi></addata></record>
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title	A novel chelatofore functionalized spiropyran of the 2-oxaindane series
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