Natural alkaloids and synthetic relatives as chiral templates of the Orito's reaction

The enantioselective hydrogenation of methyl or ethyl pyruvate over cinchona‐platinum catalyst system (Orito's reaction) is one of the most intensively studied heterogeneous catalytic asymmetric hydrogenation reactions. Studies aiming at systematic changes of the chiral template have played a c...

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Veröffentlicht in:	Chirality (New York, N.Y.) N.Y.), 2010-01, Vol.22 (1), p.3-15
Hauptverfasser:	Tálas, Emília, Margitfalvi, József L.
Format:	Artikel
Sprache:	eng
Schlagworte:	activated ketones Alkaloids Alkaloids - chemistry amines aminoalcohols Asymmetry Catalysis Catalysts Chirality cinchona alkaloids Derivatives enantioselective hydrogenation heterogeneous catalysis Hydrogenation isocinchonines Pt/Al2O3 Pyruvates Stereoisomerism
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