An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

A chiral pseudo-C(3)-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-12 (46), p.10169-10171
Hauptverfasser: Axe, Philip, Bull, Steven D, Davidson, Matthew G, Jones, Matthew D, Robinson, Diane E J E, Mitchell, William L, Warren, John E
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Mesylates - chemistry
Molecular Conformation
Stereoisomerism
Sulfoxides - chemistry
Titanium - chemistry
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Zusammenfassung:A chiral pseudo-C(3)-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.
ISSN:1477-9226
1477-9234
DOI:10.1039/b918141p