Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids
A cationic rhodium(I)/bisphosphine complex catalyzes carboxylative cyclizations of 1,6-diynes, leading to cyclic dienyl carboxylates, in high yields with high chemo-, regio-, and stereoselectivities under mild reaction conditions.
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| Veröffentlicht in: | Organic & biomolecular chemistry 2009-01, Vol.7 (23), p.4817-4820 |
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| container_end_page | 4820 |
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| container_issue | 23 |
| container_start_page | 4817 |
| container_title | Organic & biomolecular chemistry |
| container_volume | 7 |
| creator | Tanaka, Ken Saitoh, Shunsuke Hara, Hiromi Shibata, Yu |
| description | A cationic rhodium(I)/bisphosphine complex catalyzes carboxylative cyclizations of 1,6-diynes, leading to cyclic dienyl carboxylates, in high yields with high chemo-, regio-, and stereoselectivities under mild reaction conditions. |
| doi_str_mv | 10.1039/b913344e |
| format | Article |
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| ispartof | Organic & biomolecular chemistry, 2009-01, Vol.7 (23), p.4817-4820 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkynes - chemical synthesis Alkynes - chemistry Carboxylic Acids - chemical synthesis Carboxylic Acids - chemistry Catalysis Cations - chemistry Cyclization Organometallic Compounds - chemistry Phosphines - chemistry Rhodium - chemistry Stereoisomerism |
| title | Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids |
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