First Heterotrimetallic {3 d-4 d-4 f} Single Chain Magnet, Constructed from Anisotropic High-Spin Heterometallic Nodes and Paramagnetic Spacers

First Heterotrimetallic {3 d-4 d-4 f} Single Chain Magnet, Constructed from Anisotropic High-Spin Heterometallic Nodes and Paramagnetic Spacers

Three in one: Heterotrimetallic 1D coordination polymers are designed by assembling heteronuclear nodes (see figure), {Cu2Ln}, with paramagnetic octacyanido‐metallates, [M(CN)8]3− (M=Mo, W), acting as spacers. By choosing a strongly anisotropic lanthanide (DyIII), a new single chain magnet is obtain...

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Veröffentlicht in:Chemistry : a European journal 2009-11, Vol.15 (44), p.11808-11814
Hauptverfasser: Visinescu, Diana, Madalan, Augustin M., Andruh, Marius, Duhayon, Carine, Sutter, Jean-Pascal, Ungur, Liviu, Van den Heuvel, Willem, Chibotaru, Liviu F.
Format: Artikel
Sprache:eng
Schlagworte:
copper
lanthanides
magnetic properties
molybdenum
single-chain magnets
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Zusammenfassung:Three in one: Heterotrimetallic 1D coordination polymers are designed by assembling heteronuclear nodes (see figure), {Cu2Ln}, with paramagnetic octacyanido‐metallates, [M(CN)8]3− (M=Mo, W), acting as spacers. By choosing a strongly anisotropic lanthanide (DyIII), a new single chain magnet is obtained.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.200902408