Sorption of Lead from Aqueous Solutions by Tea Wastes

Environmental contamination by heavy metals has long been a worldwide concern. Tea wastes, having porous surfaces with polar functional groups, could be a good sorbent for removal of Pb(II) from wastewaters. This study aimed to investigate the potential of tea wastes as a sorbent for removal of Pb(I...

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Veröffentlicht in:Journal of environmental quality 2009-11, Vol.38 (6), p.2260-2266
Hauptverfasser: Liu, Ni, Lin, Daohui, Lu, Huifeng, Xu, Yong, Wu, Miaolong, Luo, Jin, Xing, Baoshan
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container_issue 6
container_start_page 2260
container_title Journal of environmental quality
container_volume 38
creator Liu, Ni
Lin, Daohui
Lu, Huifeng
Xu, Yong
Wu, Miaolong
Luo, Jin
Xing, Baoshan
description Environmental contamination by heavy metals has long been a worldwide concern. Tea wastes, having porous surfaces with polar functional groups, could be a good sorbent for removal of Pb(II) from wastewaters. This study aimed to investigate the potential of tea wastes as a sorbent for removal of Pb(II) from solution and the underlying sorption mechanism. Tea wastes showed high removal efficiency for Pb(II) with a short equilibration time and high sorption capacity. The sorptive affinity increased with increasing solution pH and leveled off at about pH 5. Higher temperature led to a higher sorptive affinity, indicating the sorption being an endothermic process. Coexisting metal ions lowered the sorption of Pb(II) with an order of Ag(I) < Cu(II) < Al(III). Fourier transform infrared (FTIR) spectrometer and scanning electron microscopy (SEM) with an X-ray energy dispersion spectroscopy (EDS) accessory were used to examine the underlying mechanism of the Pb(II) sorption. Surface complex formation with carboxylic and amine groups and ion exchanges were observed to regulate the binding of Pb(II) to the tea wastes.
doi_str_mv 10.2134/jeq2009.0114
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Tea wastes, having porous surfaces with polar functional groups, could be a good sorbent for removal of Pb(II) from wastewaters. This study aimed to investigate the potential of tea wastes as a sorbent for removal of Pb(II) from solution and the underlying sorption mechanism. Tea wastes showed high removal efficiency for Pb(II) with a short equilibration time and high sorption capacity. The sorptive affinity increased with increasing solution pH and leveled off at about pH 5. Higher temperature led to a higher sorptive affinity, indicating the sorption being an endothermic process. Coexisting metal ions lowered the sorption of Pb(II) with an order of Ag(I) &lt; Cu(II) &lt; Al(III). Fourier transform infrared (FTIR) spectrometer and scanning electron microscopy (SEM) with an X-ray energy dispersion spectroscopy (EDS) accessory were used to examine the underlying mechanism of the Pb(II) sorption. Surface complex formation with carboxylic and amine groups and ion exchanges were observed to regulate the binding of Pb(II) to the tea wastes.</description><identifier>ISSN: 0047-2425</identifier><identifier>EISSN: 1537-2537</identifier><identifier>DOI: 10.2134/jeq2009.0114</identifier><identifier>PMID: 19875782</identifier><identifier>CODEN: JEVQAA</identifier><language>eng</language><publisher>Madison: American Society of Agronomy, Crop Science Society of America, Soil Science Society</publisher><subject>Adsorption ; Affinity ; aluminum ; Aquatic ecosystems ; Aquatic plants ; aqueous solutions ; Camellia sinensis ; chemical reactions ; Competition ; copper ; Efficiency ; endothermic processes ; food processing wastes ; Fourier transform infrared spectroscopy ; Fourier transforms ; Heavy metals ; High temperature ; Hydrogen-Ion Concentration ; Lead ; Lead - isolation &amp; purification ; mechanism of action ; Membrane separation ; Metals ; Metals, Heavy - chemistry ; Microscopy, Electron, Scanning ; NMR ; Nuclear magnetic resonance ; polar compounds ; pollutants ; porous media ; Scanning electron microscopy ; silver ; Sorbents ; Sorption ; Spectroscopy, Fourier Transform Infrared ; surface interactions ; Tea ; Tea - chemistry ; Temperature ; Time Factors ; Waste Disposal, Fluid ; Waste water ; Wastes ; wastewater ; wastewater treatment ; Water quality</subject><ispartof>Journal of environmental quality, 2009-11, Vol.38 (6), p.2260-2266</ispartof><rights>American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America</rights><rights>Copyright American Society of Agronomy Nov/Dec 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5194-e3f61ba2be86c5c719bb644876e3ffb21979acce07ac6cd9b451824729d9cf4a3</citedby><cites>FETCH-LOGICAL-c5194-e3f61ba2be86c5c719bb644876e3ffb21979acce07ac6cd9b451824729d9cf4a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.2134%2Fjeq2009.0114$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.2134%2Fjeq2009.0114$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19875782$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Ni</creatorcontrib><creatorcontrib>Lin, Daohui</creatorcontrib><creatorcontrib>Lu, Huifeng</creatorcontrib><creatorcontrib>Xu, Yong</creatorcontrib><creatorcontrib>Wu, Miaolong</creatorcontrib><creatorcontrib>Luo, Jin</creatorcontrib><creatorcontrib>Xing, Baoshan</creatorcontrib><title>Sorption of Lead from Aqueous Solutions by Tea Wastes</title><title>Journal of environmental quality</title><addtitle>J Environ Qual</addtitle><description>Environmental contamination by heavy metals has long been a worldwide concern. Tea wastes, having porous surfaces with polar functional groups, could be a good sorbent for removal of Pb(II) from wastewaters. This study aimed to investigate the potential of tea wastes as a sorbent for removal of Pb(II) from solution and the underlying sorption mechanism. Tea wastes showed high removal efficiency for Pb(II) with a short equilibration time and high sorption capacity. The sorptive affinity increased with increasing solution pH and leveled off at about pH 5. Higher temperature led to a higher sorptive affinity, indicating the sorption being an endothermic process. Coexisting metal ions lowered the sorption of Pb(II) with an order of Ag(I) &lt; Cu(II) &lt; Al(III). Fourier transform infrared (FTIR) spectrometer and scanning electron microscopy (SEM) with an X-ray energy dispersion spectroscopy (EDS) accessory were used to examine the underlying mechanism of the Pb(II) sorption. Surface complex formation with carboxylic and amine groups and ion exchanges were observed to regulate the binding of Pb(II) to the tea wastes.</description><subject>Adsorption</subject><subject>Affinity</subject><subject>aluminum</subject><subject>Aquatic ecosystems</subject><subject>Aquatic plants</subject><subject>aqueous solutions</subject><subject>Camellia sinensis</subject><subject>chemical reactions</subject><subject>Competition</subject><subject>copper</subject><subject>Efficiency</subject><subject>endothermic processes</subject><subject>food processing wastes</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Fourier transforms</subject><subject>Heavy metals</subject><subject>High temperature</subject><subject>Hydrogen-Ion Concentration</subject><subject>Lead</subject><subject>Lead - isolation &amp; purification</subject><subject>mechanism of action</subject><subject>Membrane separation</subject><subject>Metals</subject><subject>Metals, Heavy - chemistry</subject><subject>Microscopy, Electron, Scanning</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>polar compounds</subject><subject>pollutants</subject><subject>porous media</subject><subject>Scanning electron microscopy</subject><subject>silver</subject><subject>Sorbents</subject><subject>Sorption</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>surface interactions</subject><subject>Tea</subject><subject>Tea - chemistry</subject><subject>Temperature</subject><subject>Time Factors</subject><subject>Waste Disposal, Fluid</subject><subject>Waste water</subject><subject>Wastes</subject><subject>wastewater</subject><subject>wastewater treatment</subject><subject>Water quality</subject><issn>0047-2425</issn><issn>1537-2537</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqFkU1rGzEQhkVpaNwkt57TJYc0h9rR6GtWx2DSJsFQghN6FFpZG9asLUfyEvzvo8ULhR6cg0Zi5tHLzLyEfAM6YcDF9dK_Mkr1hAKIT2QEkuOY5fCZjCgV-S2YPCZfU1pSCoyi-kKOQZcosWQjIuchbrZNWBehLmbeLoo6hlVx89r50KViHtqur6ai2hVP3hZ_bdr6dEqOatsmfzbcJ-T51-3T9G48-_P7fnozGzsJWow9rxVUllW-VE46BF1VSogSVa7UFQON2jrnKVqn3EJXQkLJBDK90K4Wlp-QH3vdTQy5o7Q1qyY537Z23bdnkAsARQVk8vIgyZUAKRT_EGTAtCwBM3h1EAREzPvnKDN68R-6DF1c580YLvLUgiLL0M895GJIKfrabGKzsnFngJreSTM4aXonM34-aHbVyi_-wYN1GdB74K1p_e6gmHm4fWT9yYlB_Pv-b22DsS-xSeZ5zihwCkiVziO9A4IOsBg</recordid><startdate>200911</startdate><enddate>200911</enddate><creator>Liu, Ni</creator><creator>Lin, Daohui</creator><creator>Lu, Huifeng</creator><creator>Xu, Yong</creator><creator>Wu, Miaolong</creator><creator>Luo, Jin</creator><creator>Xing, Baoshan</creator><general>American Society of Agronomy, Crop Science Society of America, Soil Science Society</general><general>American Society of Agronomy</general><scope>FBQ</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7T7</scope><scope>7TG</scope><scope>7X2</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>88I</scope><scope>8AF</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>KL.</scope><scope>L6V</scope><scope>M0K</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P64</scope><scope>PATMY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>S0X</scope><scope>SOI</scope><scope>7SU</scope><scope>KR7</scope><scope>7QH</scope><scope>7UA</scope><scope>7X8</scope></search><sort><creationdate>200911</creationdate><title>Sorption of Lead from Aqueous Solutions by Tea Wastes</title><author>Liu, Ni ; 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Tea wastes, having porous surfaces with polar functional groups, could be a good sorbent for removal of Pb(II) from wastewaters. This study aimed to investigate the potential of tea wastes as a sorbent for removal of Pb(II) from solution and the underlying sorption mechanism. Tea wastes showed high removal efficiency for Pb(II) with a short equilibration time and high sorption capacity. The sorptive affinity increased with increasing solution pH and leveled off at about pH 5. Higher temperature led to a higher sorptive affinity, indicating the sorption being an endothermic process. Coexisting metal ions lowered the sorption of Pb(II) with an order of Ag(I) &lt; Cu(II) &lt; Al(III). Fourier transform infrared (FTIR) spectrometer and scanning electron microscopy (SEM) with an X-ray energy dispersion spectroscopy (EDS) accessory were used to examine the underlying mechanism of the Pb(II) sorption. Surface complex formation with carboxylic and amine groups and ion exchanges were observed to regulate the binding of Pb(II) to the tea wastes.</abstract><cop>Madison</cop><pub>American Society of Agronomy, Crop Science Society of America, Soil Science Society</pub><pmid>19875782</pmid><doi>10.2134/jeq2009.0114</doi><tpages>7</tpages></addata></record>
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subjects Adsorption
Affinity
aluminum
Aquatic ecosystems
Aquatic plants
aqueous solutions
Camellia sinensis
chemical reactions
Competition
copper
Efficiency
endothermic processes
food processing wastes
Fourier transform infrared spectroscopy
Fourier transforms
Heavy metals
High temperature
Hydrogen-Ion Concentration
Lead
Lead - isolation & purification
mechanism of action
Membrane separation
Metals
Metals, Heavy - chemistry
Microscopy, Electron, Scanning
NMR
Nuclear magnetic resonance
polar compounds
pollutants
porous media
Scanning electron microscopy
silver
Sorbents
Sorption
Spectroscopy, Fourier Transform Infrared
surface interactions
Tea
Tea - chemistry
Temperature
Time Factors
Waste Disposal, Fluid
Waste water
Wastes
wastewater
wastewater treatment
Water quality
title Sorption of Lead from Aqueous Solutions by Tea Wastes
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