Atom-Transfer Radical Addition Reactions Catalyzed by RuCp Complexes: A Mechanistic Study

Kinetic and spectroscopic analyses were performed to gain information about the mechanism of atom‐transfer radical reactions catalyzed by the complexes [RuCl2Cp*(PPh3)] and [RuClCp*(PPh3)2] (Cp*=pentamethylcyclopentadienyl), in the presence and in the absence of the reducing agent magnesium. The rea...

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Veröffentlicht in:	Chemistry : a European journal 2009-11, Vol.15 (43), p.11601-11607
Hauptverfasser:	Fernández-Zúmel, Mariano A., Thommes, Katrin, Kiefer, Gregor, Sienkiewicz, Andrzej, Pierzchala, Katarzyna, Severin, Kay
Format:	Artikel
Sprache:	eng
Schlagworte:	atom transfer homogeneous catalysis kinetics radical reactions ruthenium
Online-Zugang:	Volltext
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