Lowest Singlet and Triplet States of the Oxyallyl Diradical
Small S–T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55±2) meV in adiabatic energy.
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2009-10, Vol.48 (45), p.8509-8511 |
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| container_end_page | 8511 |
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| container_issue | 45 |
| container_start_page | 8509 |
| container_title | Angewandte Chemie (International ed.) |
| container_volume | 48 |
| creator | Ichino, Takatoshi Villano, Stephanie M Gianola, Adam J Goebbert, Daniel J Velarde, Luis Sanov, Andrei Blanksby, Stephen J Zhou, Xin Hrovat, David A Borden, Weston Thatcher Lineberger, W. Carl |
| description | Small S–T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55±2) meV in adiabatic energy. |
| doi_str_mv | 10.1002/anie.200904417 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2009-10, Vol.48 (45), p.8509-8511 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_734098417 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | oxyallyl compounds photoelectron spectroscopy radicals reactive intermediates |
| title | Lowest Singlet and Triplet States of the Oxyallyl Diradical |
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