Kinetics, Thermodynamics, and Modeling of Complex Formation between Calix[4]biscrowns and Cesium

Complex formations between calix[4]arene-bis(crown-6-ether) calix-COU2 (A1) and the tetrasulfonated species calix-COUSULF (A2) with Cs+ are investigated in water and ethanol, and in 9:1 (M1) and 1:9 (M2) H2O/EtOH v:v mixtures, by chemical relaxation and molecular modeling. In ethanol and M2, two Cs+...

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Veröffentlicht in:	The journal of physical chemistry. B 2009-10, Vol.113 (43), p.14247-14256
Hauptverfasser:	Korovitch, Alexandre, Mulon, Jean-Baptiste, Souchon, Vincent, Lion, Claude, Valeur, Bernard, Leray, Isabelle, Ha-Duong, Nguyêt-Thanh, Chahine, Jean-Michel El Hage
Format:	Artikel
Sprache:	eng
Schlagworte:	B: Statistical Mechanics, Thermodynamics, Medium Effects
Online-Zugang:	Volltext
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