Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity
This critical review discusses historical and contemporary research in the field of transition metal-catalyzed carbon-hydrogen (C-H) bond activation through the lens of stereoselectivity. Research concerning both diastereoselectivity and enantioselectivity in C-H activation processes is examined, an...
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| Veröffentlicht in: | Chemical Society reviews 2009-01, Vol.38 (11), p.3242-3272 |
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| container_issue | 11 |
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| container_title | Chemical Society reviews |
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| creator | Giri, Ramesh Shi, Bing-Feng Engle, Keary M Maugel, Nathan Yu, Jin-Quan |
| description | This critical review discusses historical and contemporary research in the field of transition metal-catalyzed carbon-hydrogen (C-H) bond activation through the lens of stereoselectivity. Research concerning both diastereoselectivity and enantioselectivity in C-H activation processes is examined, and the application of concepts in this area for the development of novel carbon-carbon and carbon-heteroatom bond-forming reactions is described. Throughout this review, an emphasis is placed on reactions that are (or may soon become) relevant in the realm of organic synthesis (221 references). |
| doi_str_mv | 10.1039/b816707a |
| format | Article |
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| ispartof | Chemical Society reviews, 2009-01, Vol.38 (11), p.3242-3272 |
| issn | 0306-0012 1460-4744 |
| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Catalysis Organic Chemicals - chemical synthesis Stereoisomerism Transition Elements |
| title | Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity |
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